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Pyrolysis Kinetics of Paper Mixtures in Municipal Solid Waste.pdf

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Pyrolysis Kinetics of Paper Mixtures in Municipal Solid Waste

J. Chem. T ech. Biotechnol. 1997, 68, 65è74 Pyrolysis Kinetics of Paper Mixtures in Municipal Solid Waste Chao-Hsiung Wu* Department of Environmental Engineering, Da-Yeh Institute of Technology, Chang-Hwa 515, Taiwan Ching-Yuan Chang Jyh-Ping Lin Graduate Institute of Environmental Engineering, National Taiwan University, Taipei 106, Taiwan (Received 25 March 1996 ; revised version received 18 July 1996 ; accepted 5 August 1996 Abstract : The pyrolysis kinetics of a mixture of the four principal papers (uncoated and coated printing/writing papers, newsprint, and tissue paper) in municipal solid waste (MSW) was investigated with a thermal gravimetric analysis (TGA) reaction system. The experiments were carried out in a nitrogen environment over the temperature range of 450 to 900 K at various constant heating rates of 1, 2, and 5 K min~1. The results indicated that there were two principal reactions in the TGA curves as distinguished by the two signiDcant and distinct mass changes over the experimental conditions. The pyrolysis of a paper mixture can be adequately described by a two reaction model. The e?ect of inter- action between the components of a paper mixture on the pyrolysis rate was insigniDcant. The results for the pyrolysis rates of paper mixtures with slow heating rates can be represented by the weighting sum of the corresponding pyrolysis rates of the components of papers in MSW. The experimental results were satisfactorily Dtted by the proposed chemical reaction kinetic equations and able to provide useful data for the design of a pyrolytic processing system for the waste papers in MSW. Key words : pyrolysis, waste paper, thermal gravimetric analysis NOTATION A Pre-exponential factor of Arrhenius-term (s~1) A1, A2 A of pyrolysis reactions (1) and (2) of single components (s~1) A ij A of pyrolysis reaction j of paper i in paper mixture (s~1) C Solid residues from reaction (2) E Activation energy (kcal mol~1) E1, E2 E of pyrolysis reactions (1) and (2) o