纳米SiO2与聚合铝对含表面活性剂原水的絮凝效果研究.doc

纳米SiO2与聚合铝,2，1,2，李冬梅,3，1,2，杨柳1,2，张丽娟1,2 (1.湖南大学土木工程学院，长沙410082； 3.广东工业大学建设学院，广州 510500)高岭土颗粒表面ζ电位增加纳米SiO2显著提高PAC对与SDS的去除效果悬浊液中絮体粒径大，，沉速加快，分维值下降。olymeric Aluminium Chloride Shi Zhou1,2, Wang Qiao1,2, Li Dongmei2,3, Chen Shiyang1,2, Yang Liu1,2, Zhang Lijuan1,2 (1. Key Laboratory of Building Safety and Energy Efficiency, Ministry of Education, Hunan University, Changsha 410082, China, College of Civil Engineering, Hunan University, Changsha 410082, China， 2. College of Construction, Guangdong University of Technology, Guangzhou 510500, China) Abstract: Dynamic coagulation experiments and quiescent settling experiments were performed with adding silica nano-particles and polymeric aluminium chloride (PAC) to raw water (C0=6NTU, T=6℃±2℃) containing an anionic surfactant-sodium dodecyl sulphate (SDS) . The dynamic flocculation process of kaolin particles with SDS and the morphological characteristics of flocs fractal structures were investigated with the aid of image analysis technology and the fractal theory. And turbidity and SDS removal efficiency by silica nano-particles and PAC were also evaluated. The results show that: ①When SDS presented, the absolute value of Zeta potential on the surfaces of Kaolin particles increased, and the particle size of kaolin increased slightly. ②Adding the PAC decreases residual turbidity and SDS markedly and slightly, respectively. Comparison with PAC, addition of silica nano-particles resulted in the residual turbidity in solution relatively high, and the SDS being more favorably removed. ③Increase of temperature can improve the removal efficiency of SDS. ④The presentation of silica nano-particles dramatically enhanced the removal of turbidity and SDS with PAC as the flocculant, resulting in bigger size of flocs with increased internal porosity, settling velocity, and decreased value of fractal dimension. Key words: silica nano-particles; polyaluminium chloride; anionic surfactant; fractal dimension; flocculation efficiency; morphol