Adsorption of p-nitroaniline from aqueous solutions onto activated carbon fiber.pdfVIP

Adsorption of p-nitroaniline from aqueous solutions onto activated carbon fiber.pdf

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Adsorption of p-nitroaniline from aqueous solutions onto activated carbon fiber

A p K G a b a A R R 2 A A K A p A K 1 m a t o a a n p i c t h p m d 0 dJournal of Hazardous Materials 166 (2009) 1180–1185 Contents lists available at ScienceDirect Journal of Hazardous Materials journa l homepage: www.e lsev ier .com/ locate / jhazmat dsorption of p-nitroaniline from aqueous solutions onto activated carbon fiber repared from cotton stalk unquan Lia,b, Zheng Zhenga,?, Jingwei Fenga, Jibiao Zhanga, Xingzhang Luoa, uohua Zhaoa, Xingfa Huanga State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093, China Nanjing Agricultural University, Nanjing 210031, China r t i c l e i n f o rticle history: eceived 16 January 2008 eceived in revised form 1 September 2008 ccepted 4 December 2008 vailable online 9 December 2008 eywords: a b s t r a c t Activated carbon fiber prepared from cotton stalk was used as an adsorbent for the removal of p- nitroaniline (PNA) from aqueous solutions. Liquid phase adsorption experiments were conducted and the maximum adsorptive capacity was determined. The effect of experimental parameters such as pH, salinity and temperature on the adsorption was studied. The obtained experimental data were then fit- ted with the Langmuir, Freundlich and Redlich-Peterson models to describe the equilibrium isotherms. The kinetics rates were modeled by using the pseudo-first-order and pseudo-second-order equations. The results indicated that cotton stalk activated carbon fiber (CS-ACF) is an effective adsorbent for the removal of PNA from aqueous solutions. The maximum adsorption capacity of 406mgg?1 wasctivated carbon fiber -Nitroaniline dsorption isotherm inetics achieved at the initial PNA concentration of 200mgL?1. The optimum pH for the removal of PNA was found to be 7.6. The presence of ammonium chloride proved to be favorable for the process of adsorp- tion. The adsorption amount decreased with increasing temperature. The Redlich-Peterson model was found to best represent t

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