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Adsorption of p-nitroaniline from aqueous solutions onto activated carbon fiber
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dJournal of Hazardous Materials 166 (2009) 1180–1185
Contents lists available at ScienceDirect
Journal of Hazardous Materials
journa l homepage: www.e lsev ier .com/ locate / jhazmat
dsorption of p-nitroaniline from aqueous solutions onto activated carbon fiber
repared from cotton stalk
unquan Lia,b, Zheng Zhenga,?, Jingwei Fenga, Jibiao Zhanga, Xingzhang Luoa,
uohua Zhaoa, Xingfa Huanga
State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093, China
Nanjing Agricultural University, Nanjing 210031, China
r t i c l e i n f o
rticle history:
eceived 16 January 2008
eceived in revised form
1 September 2008
ccepted 4 December 2008
vailable online 9 December 2008
eywords:
a b s t r a c t
Activated carbon fiber prepared from cotton stalk was used as an adsorbent for the removal of p-
nitroaniline (PNA) from aqueous solutions. Liquid phase adsorption experiments were conducted and
the maximum adsorptive capacity was determined. The effect of experimental parameters such as pH,
salinity and temperature on the adsorption was studied. The obtained experimental data were then fit-
ted with the Langmuir, Freundlich and Redlich-Peterson models to describe the equilibrium isotherms.
The kinetics rates were modeled by using the pseudo-first-order and pseudo-second-order equations.
The results indicated that cotton stalk activated carbon fiber (CS-ACF) is an effective adsorbent for
the removal of PNA from aqueous solutions. The maximum adsorption capacity of 406mgg?1 wasctivated carbon fiber
-Nitroaniline
dsorption isotherm
inetics
achieved at the initial PNA concentration of 200mgL?1. The optimum pH for the removal of PNA was
found to be 7.6. The presence of ammonium chloride proved to be favorable for the process of adsorp-
tion. The adsorption amount decreased with increasing temperature. The Redlich-Peterson model was
found to best represent t
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