INF-水草C3N4.pdf

Supporting Information AGraphitic-C3N4 “Seaweed” Architecture for Enhanced Hydrogen Evolution** Qing Han, Bing Wang, Yang Zhao, Chuangang Hu, and Liangti Qu* anie_201504985_sm_miscellaneous_information.pdf Supplementary Information Experimental Photochemical measurement Wavelength dependence of H2 evolution rate was measured by using an appropriate band pass filter (400, 420, 500, 550 and 600 nm, respectively) to perform the water splitting experiment under the designated monochromic light. The intensity of the monochromic light was averaged at 5 representative points (CEL-NP 2000 spectroradiometer) and the active area of the reactor was approximately 50.3 cm2. The external quantum yield was then calculated by the following Equation (1): 100 photonsincident ofnumber evovled molecules H ofamount 2 =Φ 2 ? ? (1) The turnover number (TON) was estimated by the following Equation (2): ystphotocatal on the platinum of moles evovled molecules H of moles =TON 2 (2) The transient photocurrent measurements were performed on the Keithley 6300 semiconductor parameter analyzer under an applied bias of 0.1 V in a conventional three electrode cell where a sample-coated clean fluoride-tin oxide (FTO) glass, Pt wire and a Ag/AgCl electrode were used as the working electrode, counter electrode and reference electrode, respectively. The aqueous solution of 0.2 M Na2SO4 purged with nitrogen gas was used as the electrolyte. Scheme S1. Schematic of g-C3N4 (550) “seaweed” formation process. Fabrication of g-C3N4 “seaweed” architectures consisting of 1D porous fibers connected together is illustrated in Scheme S1. The changes for freeze-dried hydrothermal treatment dicyandiamide (HTD) are shown in Figure S12. The product of freeze-dried HTD exhibits several strong bands between 1350 and 1700 cm-1, which correspond to the characteristic CN heterocycles. Remarkably, a strong split band around 800 cm-1 was observed, which correspond to the triazine