A Coupled Optical-Electrical Multiphysics Study on the Effect of Nanoparticle Geometry.docVIP

A Coupled Optical-Electrical Multiphysics Study on the Effect of Nanoparticle Geometry.doc

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This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes. Article /journal/apchd5 Enhanced Light Trapping and Power Conversion E?ciency in Ultrathin Plasmonic Organic Solar Cells: A Coupled Optical-Electrical Multiphysics Study on the E?ect of Nanoparticle Geometry Sungjun In,? Daniel R. Mason,? Hyunho Lee,? Mi Jung,§ Changhee Lee,? and Namkyoo Park*,? ?Photonic Systems Laboratory and ?Organic Semiconductor Laboratory, School of EECS, Seoul National University, Seoul 151-744, South Korea §Sensor System Research Center, Korea Institute of Science and Technology, Seoul 136-791, South Korea *S Supporting Information ABSTRACT: Plasmonic e?ects associated with localized surface plasmon (LSP) resonances such as strong light trapping, large scattering cross-section, and giant electric field enhancement have received much attention for the more e?cient harvesting of solar energy. Notably, even as the thickness of the active layer is significantly reduced, the optical absorption capability of a solar cell could be maintained with the incorporation of plasmonic e?ects. This is especially important for the development of bulk heterojunction (BHJ) organic solar cells (OSCs), where the short exciton di?usion length, low carrier mobility, and strong charge recombination in organic materials strongly favors the use of optically thin active layers (100 nm). However, the disappointing performance improvements obtained with plasmonic e?ects in the majority of BHJ OSCs realized to date suggests that plasmonic e?ects are yet to be fully taken advantage of; for example, in thick active layer OSCs (100 nm), the optical absorption is already high, even in the absence of plasmonic e?ects, while in thin active layer OSCs (100 nm), insu?cient attention has been given to the analysis of plasmonic e?ects, such as the impact of plasmonic nanoparticle (N

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