A method for simultaneously improving the flame retardancy and toughness of PLA.pdf

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A method for simultaneously improving the flame retardancy and toughness of PLA.pdf

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A method for simultaneously improving the flame retardancy and toughness of PLA

Research ArticleReceived: 30 March 2010, Revised: 26 April 2010, Accepted: 30 April 2010, Published online in Wiley Online Library: 15 July 2010() DOI: 10.1002/pat.1760A method for simultaneously improving the flame retardancy and toughness of PLA Yan-Peng Songa, De-Yi Wanga*, Xiu-Li Wanga**, Ling Lina and Yu-Zhong WangaIn order to modify the brittleness and flame retardanPolym. Advt properties of poly(lactic acid) (PLA), a series of flame retardant toughened PLA composites were prepared using poly(ethylene glycol) 6000 (PEG6000) as a toughening and charring agent together with ammonium polyphosphate (APP) as an acid source and blowing agent. The fire and thermal behavior of PLA/PEG/APP composites was evaluated by limiting oxygen index (LOI), UL-94, cone calorimeter, and thermogravimetric analysis (TGA). The results showed that the PLA/PEG/APP system had good charring ability and could improve the flame retardancy of PLA. When the content of APP in the composites was more than 5wt%, all samples could reach UL-94 V-0 rating. The results of mechanical property tests demonstrated that the brittleness of PLAwas also improved after blended with PEG6000. All the PLA/PEG/APP composites with an APP content of less than 10wt% showed an obvious neck and fracture behavior, that is, the tensile behavior of PLAwas changed from brittle to ductile. Copyright 2010 John Wiley Sons, Ltd. Keywords: poly(lactic acid) (PLA); APP; PEG; flame-retardant; toughening* Correspondence to: D.-Y. Wang, Center for Degradable and Flame-Retardant Polymeric Materials (ERCEPM-MoE), College of Chemistry, State Key Labora- tory of Polymer Materials Engineering, Sichuan University, Chengdu 610064, China E-mail: xiuliwang1@163.com ** Correspondence to: X.-L. Wang, Center for Degradable and Flame-Retardant Polymeric Materials (ERCEPMMoE), College of Chemistry, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610064, China a Y.-P. Song, D.-Y. Wang, L. Lin, Y.-Z. Wang Ce