Ti基添加剂对Mg2FeH6放氢性能的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 26(2016) 791−798 Effects of Ti-based additives on Mg2FeH6 dehydrogenation properties Chen-chen XU, Xue-zhang XIAO, Jie SHAO, Lang-xia LIU, Teng QIN, Li-xin CHEN State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China Received 6 January 2015; accepted 4 April 2015 Abstract: Mg FeH doped with and without Ti and its alloys (TiMn , TiAl) were prepared combing ball milling and heat treatment. 2 6 2 The effects of these additives on the dehydrogenation performance of Mg2FeH6 were studied systematically. The results show that all additives have favor influence on improving the hydrogen desorption property of Mg FeH . Especially, TiMn exhibits prominent 2 6 2 effect on enhancing the dehydrogenation kinetics of Mg FeH . Moreover, the activation energy of TiMn -doped Mg FeH calculated 2 6 2 2 6 by Kissinger equation is 94.87 kJ/mol, which is 28 kJ/mol lower than that of the undoped Mg FeH . The cycling tests suggest that the 2 6 improved dehydrogenation kinetics of Mg FeH doped by TiMn can maintain in the second cycle. 2 6 2 Key