基于响应面法优化激光选区熔化成型CoCrMo合金工艺及其电化学行为.pdfVIP

第 24卷第 10期 中国有色金属学报 2014年 10月 Volume 24 Number 10 The Chinese Journal of Nonferrous Metals October 2014 文章编号：1004-0609(2014)10-2497-09 基于响应面法优化激光选区熔化成型 CoCrMo合金工艺及其电化学行为 王赟达1，杨永强1，宋长辉1，刘凤美2，麦淑珍 摘 要：为了快速直接制造结构复杂、性能优异的个性化医用金属植入体，保证成型件具有良好的组织结构和生 物特性，通过激光选区熔化技术对满足ASTMF75要求的CoCrMo合金进行增材制造。通过正交试验和响应曲面设 计方法优化致密度工艺参数，观察成型件的微观组织，分析试样在模拟人体体液环境中的耐腐蚀性，并探究热处 理工艺对其耐腐蚀性的影响。结果表明：在激光功率 168 W、扫描间距 0.06 mm、扫描速度 550 mm/s时，成型零 件的致密度可以达到 98.58%，且微观组织均匀。电化学实验结果显示试样的腐蚀电流密度值约为 40 μA/cm 1 (1. 华南理工大学 机械与汽车工程学院，广州 510640； 2. 广州有色金属研究院，广州 510650) 2，经 过退火热处理后，腐蚀电流密度仅为 20.86 μA/cm2 中图分类号：TG665；TH164 文献标志码：A ，其耐腐蚀性能优于铸造CoCrMo合金的，这为选区激光熔化 成型CoCrMo合金在医学植入体方面的应用提供了依据。 关键词：CoCrMo合金；激光选区熔化；致密度；响应曲面；耐腐蚀性；热处理 Process optimization and electrochemical behavior of CoCrMo alloy fabricated by selective laser melting based on response surface method WANG Yun-da1, YANG Yong-qiang1, SONG Chang-hui1, LIU Feng-mei2, MAI Shu-zhen Abstract: In order to directly fabricate personalized medical metallic implants with complex structure and excellent properties and ensure the parts have good microstructure and biological characteristics, the CoCrMo alloy satisfying the requirement of ASTMF75 is fabricated by selective laser melting (SLM) technology. The parameters of relative density were optimized by orthogonal experiment and response surface design. The microstructure of the specimens was observed, and the corrosion characteristic of the samples in simulated body fluid environment was analyzed while the influence of heat treatment process on the corrosion resistance was explored. The results show when the laser power is 168 W, the scanning space is 0.06 mm and the scanning speed is 550 mm/s, the relative density of CoCrMo alloy samples fabricated by SLM can reach 98.58%, and the microstructure is homogeneous. The electrochemical experimental results demonstrate that the corros