钨纤维增强钨基合金挤压棒坯的脱脂工艺.pdfVIP

第 16 卷第 3 期 粉末冶金材料科学与工程 2011 年 6 月 Vol.16 No.3 Materials Science and Engineering of Powder Metallurgy Jun. 2011 钨纤维增强钨基合金挤压棒坯的脱脂工艺 刘文胜，贺柳青，马运柱，张佳佳 ( 中南大学 粉末冶金国家重点实验室，长沙 410083) 摘 要：在 93W-Ni-Fe 粉末中添加长 2～3 mm 的短钨纤维，用粉末挤压成形方法制备纤维定向排布强韧化的钨合 金棒坯。对蜡基粘结剂挤压喂料进行 DSC-TG 热分析，采用扫描电镜、光学电镜对热脱脂后的挤压棒坯微观结构 和表面形貌进行测试与表征，对比研究含纤维与不含纤维挤压棒坯的热脱脂行为。结果表明：1)挤压棒坯在热脱 脂过程中极易产生开裂等缺陷；2)经优化脱脂工艺，含纤维与不含钨纤维挤压棒坯表面和内部结构均得到明显改 善；3)钨纤维的添加为 93W-Ni-Fe 棒坯脱脂提供优先脱脂通道，有利于粘结剂的脱除，并在脱脂过程中对坯体起 强化作用。 关键词：钨基合金挤压棒；粘结剂；热脱脂；钨纤维 中图分类号：TF124.39 文献标识码：A 文章编号：1673-0224(2011)3-361-07 Debinding process of tungsten-based alloy extruded bar reinforced with tungsten fibers LIU Wen-sheng, HE Liu-qing, MA Yun-zhu, ZHANG Jia-jia (State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract: Oriented, aligned short tungsten fibers reinforced tungsten-based alloy (93W-Ni-Fe) extruded bar was prepared by powder extrusion molding process. Mechanical properties of the bar could be improved by fiber reforcing and toughening. The extrusion feedstock was analyzed by DSC-TG thermal analysis, the inner microstructure and surface morphology were observed and characterized by scanning electron microscope and optical electron microscope. The thermal debinding behavior was studied by comparing the extrude bars with and without tungsten fibers. The results show that: 1) surface and inner structures of debinding bars without tungsten fibers could be improved after optimizing the process. 2) glabrous and defectless debinding bars w