8 - aminoquinoline substituted benzamide derivatives of mercury ion and copper ion based.docVIP

 PAGE \* MERGEFORMAT 13 8 - aminoquinoline substituted benzamide derivatives of mercury ion and copper ion based Study: Chinese Han Lifeng Wu-Lin Yi Bin Jiang Yun-Bao Nguyen [Abstract] designed and synthesized to identify the metal ion fluorescence sensing elements 8 - aminoquinoline substituted benzamide derivatives, characterized by nuclear magnetic resonance spectroscopy and mass spectrometry of its structure, using its spectral properties of substances on the series of transition metal ions Cu2 +, Hg2 +, Pb2 +, Zn2 +, Ni2 + and Cd2 + identify the nature of a preliminary study of its recognition mechanism. experimental results show that: in acetonitrile, 8 - aminoquinoline benzamide absorption spectrum in the 509 nm Department of Cu2 + have to respond, the solution from colorless to red, and their fluorescence spectra Hg2 + and Cu2 + have a good selectivity, fluorescence enhancement ratio of up to 368 and 192, respectively, combined with metal ions to form 1:1 complexes. [Keywords:] 8 - aminoquinoline substituted benzamide derivatives, absorption spectrum, fluorescence enhancement, copper, mercury, molecular recognition Abstract The novel 8-Aminoquinoline (8-AQ) derivatives receptor was designed and synthesized.Its structure was characterized by NMR and ESI-MS.It was investigated to recognize metal ions such as Cu2 +, Hg2 +, Pb2 +, Zn2 +, Ni2 + and Cd2 + via its absorption and fluorescence spectra.The recognition mechanism and binding mode were discussed.The results showed that 8-AQ derivatives 1 coordinated with Cu2 + can induce a new absorption peak at 509 nm, which turned the solution to red from colorless.In acetonitrile Hg2 + and Cu2 + induced dramatic enhancement in the fluorescence of the derivation 1 by 368 and 192 folds.Job plot showed 1:1 stoichiometry between 8-AQ and Cu2 + or Hg2 +. Keywords 8-Aminoquinoline derivatives, Absorption spectra, Fluorescence enhancement, Copper, Mercury, Molecular, Recognition 1 Introduction 8 - a