Accelerated Solvent Extraction and Gas Chromatography Mass Spectrometry sludge sediment and soil samples in the synthetic musks.docVIP

 PAGE \* MERGEFORMAT 13 Accelerated Solvent Extraction and Gas Chromatography Mass Spectrometry sludge sediment and soil samples in the synthetic musks Of: Huzheng Jun Shi Yali Cai Yaqi [Abstract] established the sludge, sediment and soil samples in the analysis of 7 kinds of method of synthesis of musk. By accelerated solvent extraction (ASE) extraction, silica gel / neutral alumina column purified, concentrated and set the volume wash off the liquid, with the GC SIM MS detection. The method of alternative fluoranthene d10 standard sample recovery was 89.7% 110.9%. c13 to HCB as internal standard, 7 kinds of synthetic musk linear range of 0.6 ~ 100.0 μg / kg. sediment and soil in the musk of the detection limit was 0.25 ~ 0.33 μg / kg (S / N = 3); sludge detection limit is 2.9 ~ 3.3 μg / kg (S / N = 3 .) matrix spike recovery experiments, the average recovery was 83.6% ~ 105.1%; RSD was 3.2% to 9.8%. This method is accurate, rapid, and can be used for the detection of real samples. [Keywords:] accelerated solvent extraction; synthetic musk; sludge; sediment; soil; silica / neutral alumina column; gas chromatography mass spectrometry Abstract A rapid, simple accelerated solvent extraction (ASE) method has been developed to determine seven synthetic musks in sewage sludge, sediment and soil by GC MS. After extraction, samples were cleaned up by silica gel / neutral Al2O3column. Then final eluate was concentrated before injection. Identification was carried out by GC MS in the Selective Ion Monitor (SIM) mode. Using the method, the recovery of fluenthene d10, surrogate standard, was from 89.7% to 110.9%. The detection limits of musks were from 2.9 to 3.3 μg / kg in sewage sludge and 0.25-0.33 μg / kg in sediment and soil (S / N = 3). Using hexachlorobenzene (HCB) 13C6 as the internal standard, good linear calibrations were obtained in the range of 0.6-100 μg / kg. The average recoveries were in the range of 83.6% -105.1% when the spiked concentration