特定形貌γ-Al2O3纳米晶的-中南民族大学学报(自然科学版).doc

特定形貌γ-Al2O3纳米晶的 可控合成及其表征 李金林，张 鑫，王 立，张煜华 ( 中南民族大学 催化材料科学湖北省暨国家民委-教育部共建重点实验室，武汉430074) 摘 要 利用水热重结晶方法制备了不同形貌γ-Al2O3纳米晶，系统考察了铝源、溶剂、pH值、结构导向剂等因素对γ-Al2O3纳米晶形貌的影响.采用TEM、XRD、氮气物理吸附-脱附等方法对不同形貌的样品进行了表征.结果显示：以异丙醇铝为铝源，以水为溶剂，调变pH，水热处理后得到了均一的二维结构γ-Al2O3纳米晶，该纳米晶呈现比较规整的菱形片状结构，含有单一孔径分布，其主要外暴露晶面是(110)晶面；以硝酸铝为铝源，水合肼为结构导向剂，水热处理后得到了均一的一维结构γ-Al2O3纳米晶，该纳米晶呈现比较规整的棒状结构；以铝溶胶为铝源，油酸钠为结构导向剂，水热处理后得到了均一的零维结构γ-Al2O3纳米晶.基于水热法合成中上述因素对γ-Al2O3晶体形貌的影响规律，能够可控合成不同形貌的γ-Al2O3纳米晶；相关表征结果显示，不同形貌的γ-Al2O3纳米晶具有不同的外晶面结构和性质. 关键词 纳米晶；氧化铝；纳米结构；外表面 中图分类号 O643.36 文献标识码 A 文章编号 1672-4321(2016)04- Shape-controlled Synthesis of γ-Al2O3 Nanocrystals Li Jinlin，Zhang Xin，Wang Li，Zhang Yuhua ( Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission Ministry of Education，Hubei Province，South-Central University for Nationalities，Wuhan 430074，China) Abstract: γ-Al2O3 nanocrystals of different morphologies were synthesized by a hydrothermal method. The influence factors on shape-controlled synthesis of nanocrystals, such as solvent, pH and structure directing agent were investigated. These alumina samples were characterized by TEM, XRD, N2 adsorption-desorption. TEM results show that γ-Al2O3 nanosheets (two-dimensional nanostructures) were obtained from aluminum isopropoxide in water through a hydrothermal method. γ-Al2O3 nanosheets with narrow pore size distribution have regular shaped morphologies. HRTEM results show that the (110) crystal planes of γ-Al2O3 are one of the lateral surfaces of nanosheets. Moreover, γ-Al2O3 nanorods (one-dimensional nanostructures) and nanoparticles (zero-dimensional nanostructures) were synthesized from different precursors and solvents by the hydrothermal method. The lateral surfaces of γ-Al2O3 nanocrystals with different morphologies possesses different two-dimensional structures of crystal planes. Keywords nanocrystals；aluminum；nanostructures；lateral surfaces 收稿日期 2016-07-27 作者简介 李金林( 1963-) ，男，教授，博士生导师，研究方向: 多相催化，E-mail:  HYPERLINK m