高铁铝土矿与硫酸氢铵混合焙烧工艺..pdfVIP

第?24?卷第?3?期 中国有色金属学报? 2014?年?3?月? Volume?24?Number?3? The?Chinese?Journal?of?Nonferrous?Metals? March 2014? 文章编号：1004-0609(2014)03-0808-06? 高铁铝土矿与硫酸氢铵混合焙烧工艺 辛海霞，吴 艳，刘少名，翟玉春? (东北大学 材料与冶金学院，沈阳? 110004)? 摘 要：针对传统处理高铁铝土矿能耗高、金属提取率低等缺点，提出硫酸氢铵焙烧工艺。在分析广西高铁铝土 矿热分解过程的基础上，研究硫酸氢铵加入量、焙烧温度和焙烧时间等工艺参数，采用?XRD?对反应产物物相进 行表征。结果表明：在硫酸氢铵与铝土矿质量比为 3.5:1、焙烧温度为 450?℃、焙烧时间 60?min? 的条件下，铝和 铁的提取率分别为 93%和 95%以上；铝反应的产物为 NH4Al(SO4)2，铁反应的中间产物为(NH4)3Fe(SO4)3，最终产 物为 NH4Fe(SO4)2。该工艺具有焙烧温度低、金属提取率高等特点，对广西高铁铝土矿的开发利用具有重要意义。 关键词：高铁铝土矿；硫酸氢铵；焙烧工艺 中图分类号：TF821? 文献标志码：A? Roasting?process?of?mixture?of? high?ferric?bauxite?and?ammonium?bisulfate? XIN?Hai-xia,?WU?Yan,?LIU?Shao-ming,?ZHAI?Yu-chun? (School?of?Materials?and?Metallurgy,?Northeastern?University,?Shenyang 110004,?China)? Abstract:?A novel?process?of?roasting?high-iron?bauxite?using?ammonium?bisulfate?was proposed?to?overcome?the?defects? of? traditional? process,? such? as? high? power? consumption? and? low? extraction? rates.? First,? the? thermodynamics? in? decomposition? process? of? high-iron? gibbsitic? bauxite? resource? in? Guangxi? was? analyzed.? Then,? various? parameters? including?ammonium?bisulfate?addition,?roasting?temperature?and?roasting?time?were?investigated.?The?product?was?also? characterized?by?XRD.?The?results?show?that?extraction?rates?of?over?93%?and?95%?respectively?for?aluminum?and?iron? are?obtained?after?roasting?at?450? ℃? for?60?min?and?mass?ratio?of ammonium?bisulfate to?bauxite?being?3.5:1.?The?phase? of? alumina-containing? compounds? is? always? NH4Al(SO4)2? in? prod