Isoproturon imprinted film sensor sensitive.docVIP

 PAGE \* MERGEFORMAT 14 Isoproturon imprinted film sensor sensitive [Abstract] weak acid (pH 5.5) conditions, the use of electricity in the gold electrode polymerization Preparation of o-aminophenol isoproturon imprinted membrane, the performance of the imprinted membrane, molecular imprinting effect and the imprinted membrane for the template molecule and its structure similar to the selective response properties were studied. with K3Fe (CN) 6 as the template base solution between the electrode and the probe, a novel method of detection of isoproturon. The sensor has good selectivity isoproturon and sensitivity to isoproturon concentration 1.0 × 10-7 ~ 4.0 × 10-4 mol / L in the range of K3Fe (CN) 6 reduced the amount of the reduction peak current was linear; detection limit of 2.95 × 10-8 mol / L. isoproturon in water content of the field was determined by recovery of 99.0% ~ 102.0%. [Key Words] molecular imprinting, electrochemical sensors, isoproturon, poly o-aminophenol 1 Introduction Molecular imprinting is a method of selective recognition of molecular imprinting [1 ~ 3]. Since the internal molecular imprinted polymer with a fixed size and shape of the cavity, and to determine the function arranged in groups, so three-dimensional structure of the template with memory function . molecularly imprinted polymer sensitive membrane stability, simple preparation, low cost, has been in the sensor of great concern [4 ~ 6]. In recent years, Western blot detection sensor technology research in pesticide also been deeply imprinted sensors the detection of atrazine, Diquat net, glyphosate, parathion and other pesticides has been reported a dozen [7], but the phenyl urea pesticide imprinted sensitive membrane sensor has not been reported. Isoproturon ( N, N-dimethyl-N ‘4-isopropyl phenyl urea) was developed in 1972 a German company Hoechst-phenyl-urea herbicide widely used on agricultural crops bud and the bud, the different levels of human toxicity, and so