Modified glassy carbon electrode of lead dioxide coating - Cyclic Voltammetry and Catalytic Properties.doc

 PAGE \* MERGEFORMAT 20 Modified glassy carbon electrode of lead dioxide coating / Cyclic Voltammetry and Catalytic Properties Of: Liu Youqin Music Man Chi Yan Xuefeng Feng Yun Xu Li [Abstract] coating / cyclic voltammetry were prepared PbO2 modified glassy carbon electrode. In Pb (NO3) 2 solution, the Pb film at -0.7 V deposited on glassy carbon electrode surface, and then in 5 mol / L NaOH solution in the 100 mV / s speed -1.0 ~ 1.0 V cyclic voltammetry 20, PbO2 films uniformly deposited on glassy carbon electrode surface. by AC impedance monitoring of each electrode modification process, environmental scanning electron microscopy characterization of the electrode surface topography. of the PbO2 film deposition mechanism and electrochemical behavior, the amount of surface coverage of active sites for the 7.5 × 10-10 mol/cm2.PbO2 H2O2 electrochemical oxidation on modified electrode showed high catalytic activity, the initial oxidation potential as low as 0.1 V, examine the factors affecting the catalytic activity. chronoamperometric determination of H2O2 (working potential 0.40 V), response time is less than 2 s; linear range was 5.0 × 10-6 ~ 5.5 × 10-4 mol / L; detection limit of 1.1 × 10-6 mol / L (N = 3). in the actual determination of H2O2 in water samples with satisfactory results. electrode at room temperature storage of 30 d, the catalytic activity. The modified electrode preparation is simple, good reproducibility, high stability. [Keywords:] lead dioxide; glassy carbon electrode; coating / cyclic voltammetry; Electrocatalysis 1 Introduction H2O2 is an important environmental and biological systems in the vehicle, its detection is of great significance. Electrochemical methods because of their sensitive, rapid, reliable and attention. In the traditional electrode directly susceptible to oxidation or reduction of H2O2 electroactive material in biological systems interference and electrode overpotential and other effects, the use of chemic