Near infrared spectroscopy analysis of residues of chlorpyrifos in water.doc

 PAGE \* MERGEFORMAT 9 Near infrared spectroscopy analysis of residues of chlorpyrifos in water On: Sun Rongmei, Li Jun Qing, Xiang Bingren, in Li Yan [Abstract] Objective To establish a rapid and efficient HPLC method for determination of chlorpyrifos. Methods Near Infrared Spectroscopy, near infrared spectroscopy the detection range 12 500 ~ 4 000 cm-1, resolution 4 cm-1, 64 times the number of scans . Results of partial least squares regression in 6 447 ~ 5 448 cm-1 range for analysis, testing the concentration range of 10 ~ 125 ng / ml,, predicted a correlation coefficient of 99.59%, root mean square error of prediction 2.29. Conclusion Near infrared spectroscopy can be used for pesticide residue analysis of chlorpyrifos. [Keywords:] chlorpyrifos, near infrared spectroscopy, partial least squares regression Chlorpyrifos (Chlorpyrifos, Dow Chemical Company in the United States developed out of an efficient, broad-spectrum, moderately toxic organophosphate insecticide, miticide, and patented (USP3244586) [1]. Chlorpyrifos can inhibit human cholinesterase enzyme activity, after accumulation in the nervous system can cause nausea, dizziness, or confusion, high concentration exposure can cause respiratory paralysis and death. Chlorpyrifos is widely used in many countries, repeated use of chlorpyrifos through soil into groundwater can in and chlorpyrifos in the water more stable [2], slow digestion, agricultural irrigation near the river can often detect chlorpyrifos [3]. If this is the groundwater used for drinking, it is necessary to monitor the concentration of chlorpyrifos. Content Analysis of chlorpyrifos used gas chromatography [4], HPLC [5] and GC-MS [6] and other methods, but traditional methods long before the processing time, and the need to consume large amounts of solvent. In this study, using near infrared spectroscopy chlorpyrifos in water features in the near infrared region to study absorption, by their characteristic absorption in