Poly-Amino modified electrode Black 10B-Nafion detection of dopamine.docVIP

 PAGE \* MERGEFORMAT 16 Poly-Amino modified electrode Black 10B/Nafion detection of dopamine Of: Wang Chunyan TANG Xiao Yan from the days of strong wind field [Abstract] electrochemical polymerization of poly amido black 10B/Nafion modified electrode, studied by cyclic voltammetry of dopamine at the modified electrode on the electrochemical behavior. In phosphate buffer solution (pH 6.0, the DA in the modifications electrode showed reversible redox peaks. The peak potential is increased with the pH value of the negative shift. dopamine oxidation peak current and the concentration of 0.2 ~ 30 μmol / L range was good and the detection limit was 1.0 × 107 mol / L. The results showed that: The modified electrode has good reproducibility, stability and strong anti-interference ability. this modified electrode for dopamine injection and detection of dopamine in bovine serum result, satisfactory. [Keywords:] modified electrode, amido black 10B, Nafion, dopamine, electrocatalysis 1 Introduction In recent years, dye polymer film modified electrodes because of its good stability, high catalytic activity, selectivity and other advantages of rapid development, and in electrocatalysis, sensors, etc. shows a good prospect [1 ~ 3]. N Black 10B are weak acid dyes, as the electrode material of modifiers has not been reported. Because of this dye with the amino and the electron donor with multiple conjugated system, thus, the reagent may also play a mediator role. In addition, the reagents are more aromatic, modified molecules increase in the number of benzene ring will help to improve the electrocatalytic activity and stability [4,5]. Dopamine (DA is an important mammalian central nervous system neurotransmitter, it is the body’s concentration and mental activity are directly related to determination of its significance. As DA has a good electrochemical activity, Electrochemical determination of the content available. However, a large number of organisms in