Preconcentration flow injection cold vapor atomic absorption fluorescence spectrometry of trace inorganic mercury in mineral water_0.doc

 PAGE \* MERGEFORMAT 14 Preconcentration flow injection cold vapor atomic absorption fluorescence spectrometry of trace inorganic mercury in mineral water Of: Zi Hong Jinggan fifty-two Hansu Ping Jiang Xianjuan Ling in the end [Abstract] of the PTFE tube knotted reactor (KR-line sorption preconcentration and cold vapor atomic fluorescence technology combined with determination of trace inorganic mercury mineral water method. Hg2 + and Hg2 + DDTC DDTC-line complex formation and adsorption the inner walls of the KR, the use of electromagnetic induction heating technology, with 20% (V / V) HNO3-line pre-heated elution and oxidation on the inner wall enriched in KR Hg2 + DDTC. eluent solution and the reaction KBH4 mercury vapor, direct associated with cold vapor atomic fluorescence was detected by .20% (V / V) HNO3 as the eluent at the same time provide a place for the hydrogenated acid medium. This method does not use a common organic eluent with a simple operation and environmental protection advantages. Analysis of 30 samples per hour, maximum adsorption ratio of 35 times, sample analysis precision RSD was 2.2% (n = 11), the detection limit (3σ) was 2.0 ng / L. [Keywords:] knotted reactor, electromagnetic induction heating, cold vapor atomic fluorescence spectroscopy, inorganic mercury, mineral water Abstract Flow injection on line sorption preconcentration and separation in a knotted reactor (KR) was coupled to cold vapor atomic fluorescence spectrometry for the determination of trace mercury in mineral water. Mercury was preconcentrated by on line formation of mercury diethyldithiocarbamate complex (Hg DDTC) and absorption of the resulting neutral complex on the inner walls of a knotted reactor. A 20% (V / V) HNO3 solution heated by electromagnetic induction heating technique was used as eluent to remove the absorbed Hg DDTC from the KR, and then the vapor mercury generated by mixing the resulting solution and KBH4 was determined on line by cold va