Effect on temperature on surface tension of a bubble and hierarchical ruptured bubbles for nanofiber fabrication.docVIP
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Effect on temperature on surface tension of a bubble and hierarchical ruptured bubbles for nanofiber fabrication
He, J.-H.: Effect on Temperature on Surface Tension of a Bubble and …
THERMAL SCIENCE, Year 2012, Vol. 16, No. 1, pp. 327-330
327
Open forum
EFFECT OF TEMPERATURE ON SURFACE TENSION
OF A BUBBLE AND HIERARCHICAL RUPTURED BUBBLES
FOR NANOFIBER FABRICATION
by
Ji-Huan He
National Engineering Laboratory for Modern Silk, College of Textile and Engineering,
Soochow University, Suzhou, China
Short paper
DOI: 10.2298/TSCI111111033H
Polymer bubbles can be used to fabrication of nanofibers using the bubble elec-
trospinning. Temperature is one of the most effective parameters to control the
spinning process. Suitable choice of inner and outer temperatures results in a
minimal surface tension. A bubble under electronic field will be broken to form
daughter bubble cascades, which can be used for nanofiber fabrication.
Key words: bubble, surface tension, bubble electrospinning, nanofiber
Introduction
Electrospinning is the simplest way to producing ultrafine fibers with diameters
ranging from 10 mm down to 10 nm by forcing a viscous polymer solution or melt through a
spinnerette with an electric field [1, 2]. When the electric force overcomes its surface tension
of the Taylor cone, a charged jet is formed.
The surface tension for the polymer solution can be expressed in the form [3]
? ? Ae?B/?
(1)
where s is the surface tension, h – the viscosity, and A and B are constants. According to
Mark-Houwink formulation [4, 5], a higher molecular weight of a solution yields a higher
viscosity:
? ? M
?
w
(2)
where M is the molecular weight, and a – the scaling exponent; the value of a lies between
w
1/3 and 1.
When the molecular weight/viscosity increases to a threshold, the polymer solution
becomes coagulated, and can not be used for fabrication of ultrafine fibers by the classical
electrospinning [6]. To overcome the problem, few technologies were appeared, among which
the vibraition-electrospinning [6] and
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