Effect on temperature on surface tension of a bubble and hierarchical ruptured bubbles for nanofiber fabrication.docVIP

Effect on temperature on surface tension of a bubble and hierarchical ruptured bubbles for nanofiber fabrication.doc

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Effect on temperature on surface tension of a bubble and hierarchical ruptured bubbles for nanofiber fabrication

He, J.-H.: Effect on Temperature on Surface Tension of a Bubble and … THERMAL SCIENCE, Year 2012, Vol. 16, No. 1, pp. 327-330 327 Open forum EFFECT OF TEMPERATURE ON SURFACE TENSION OF A BUBBLE AND HIERARCHICAL RUPTURED BUBBLES FOR NANOFIBER FABRICATION by Ji-Huan He National Engineering Laboratory for Modern Silk, College of Textile and Engineering, Soochow University, Suzhou, China Short paper DOI: 10.2298/TSCI111111033H Polymer bubbles can be used to fabrication of nanofibers using the bubble elec- trospinning. Temperature is one of the most effective parameters to control the spinning process. Suitable choice of inner and outer temperatures results in a minimal surface tension. A bubble under electronic field will be broken to form daughter bubble cascades, which can be used for nanofiber fabrication. Key words: bubble, surface tension, bubble electrospinning, nanofiber Introduction Electrospinning is the simplest way to producing ultrafine fibers with diameters ranging from 10 mm down to 10 nm by forcing a viscous polymer solution or melt through a spinnerette with an electric field [1, 2]. When the electric force overcomes its surface tension of the Taylor cone, a charged jet is formed. The surface tension for the polymer solution can be expressed in the form [3] ? ? Ae?B/? (1) where s is the surface tension, h – the viscosity, and A and B are constants. According to Mark-Houwink formulation [4, 5], a higher molecular weight of a solution yields a higher viscosity: ? ? M ? w (2) where M is the molecular weight, and a – the scaling exponent; the value of a lies between w 1/3 and 1. When the molecular weight/viscosity increases to a threshold, the polymer solution becomes coagulated, and can not be used for fabrication of ultrafine fibers by the classical electrospinning [6]. To overcome the problem, few technologies were appeared, among which the vibraition-electrospinning [6] and

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