有机化合物波谱解析课件 核磁共振部分习题及答案_3.pdfVIP

NMR problems 3rd part 1. Due to elements of symmetry within the structure of the molecule, the 13C NMR spectrum of ethane contains only a single resonance, the corresponding spectra of (CH ) CHBr and (CH ) CBr would contain 2 resonances. How many distinct 3 2 3 3 resonances are there in: 1 The 1H NMR spectrum of (CH ) C ? 3 4 2 The 13C NMR spectrum of (CH ) C ? 3 4 3 The 31P NMR spectrum of (CH CH ) PO ? 3 2 3 4 The 13C NMR spectrum of (CH CH ) PO ? 3 2 3 5 The 1H NMR spectrum of (CH CH ) PO ? 3 2 3 6 The 29Si NMR spectrum of (CH ) SiSi(Et) ? 3 3 3 7 The 1H NMR spectrum of (CH ) SiSi(Et) ? 3 3 3 8 The 13C NMR spectrum of (CH ) SiSi(Et) ? 3 3 3 Answer This is a very straightforward question once you have correctly written down the 3 dimensional structure of each of the compounds in question. The 3 dimensional geometry and in particular the symmetry associated with each compound allows you to determine which atoms are (or are not) chemically equivalent 1 (CH ) C is a tetrahedral molecule with all 4 methyl groups equivalent. In the 1H 3 4 NMR spectrum, there would be 1 NMR signal for the 4 equivalent CH groups. 3 2 (CH ) C is a tetrahedral molecule with all 4 methyl groups equivalent. In the 13C 3 4 NMR spectrum, there would be 1 NMR signal for the 4 equivale