Analysis of Gas Permeability Characteristics of Poly(Lactic Acid)Poly(Butylene Succinate) Nanocomposites英文文献资料.docVIP

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Analysis of Gas Permeability Characteristics of Poly(Lactic Acid)Poly(Butylene Succinate) Nanocomposites英文文献资料.doc

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Analysis of Gas Permeability Characteristics of Poly(Lactic Acid)Poly(Butylene Succinate) Nanocomposites英文文献资料

HindawiPublishingCorporation JournalofNanomaterials Volume2012,ArticleID249094,11pages doi:10.1155/2012/249094 ResearchArticle AnalysisofGasPermeabilityCharacteristicsof Poly(LacticAcid)/Poly(ButyleneSuccinate)Nanocomposites AmitaBhatia, RahulK.Gupta, SatiN.Bhattacharya, andHyoungJinChoi 1 1 1 2 1 RheologyandMaterialsProcessingCentre,SchoolofCivil,EnvironmentalandChemicalEngineering, RMITUniversity,Melbourne,VIC3001,Australia DepartmentofPolymerScienceandEngineering,InhaUniversity,Incheon402-751,RepublicofKorea 2 CorrespondenceshouldbeaddressedtoRahulK.Gupta,rahul.gupta@.auandHyoungJinChoi,hjchoi@inha.ac.kr Received29June2012;Revised13September2012;Accepted13September2012 AcademicEditor:SuprakasSinhaRay Copyright?2012AmitaBhatiaetal.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttributionLicense, whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited. Gas permeability and morphological properties of nanocomposites prepared by the mixing of poly(lactic acid) (PLA), poly(butylenesuccinate)(PBS),andclaywasinvestigated.WhilethecompositionofPLAandPBSpolymerswas?xedas80% and20%byweight,respectively,forallthenanocomposites,claycontentsvariedfrom1to10wt%.Fromthemorphological studiesusingbothwideangleX-raydi?ractionandtransmissionelectronmicroscopy,thenanocompositehaving1wt%ofclay was considered to have a mixed morphology of intercalated and delaminated structure, while some clusters or agglomerated particlesweredetectedfornanocompositeshaving3andmorethan3wt%ofclaycontent.However,theaverageparticlesizeof thedispersedPBSphasewasreducedsigni?cantlyfrom7μmto30–40nmwiththeadditionofclayintheblend.Theoxygen barrierpropertywasimprovedsigni?cantlyascomparedtothewatervapor.Amodelbasedongasbarrierpropertywasusedfor thevalidationoftheoxygenrelativepermeabilitiesofPLA/PBS/claynanocomposites.PLA/PBS/claynanocompositesvalidatedthe Bharadwajmodelupto3wt%ofclayco