烷基取代聚硅烷手性行为.pdfVIP

目 录 第一章 绪论····················································································1 1.1 螺旋高分子简介······································································1 1.2 螺旋高分子中手性、螺旋结构的诱导与调控···································4 1.3 螺旋聚硅烷简介······································································9 1.4 螺旋聚硅烷的手性行为的研究进展··············································12 1.5 本文主旨··············································································17 第二章 实验部分·············································································18 2.1 实验主要试剂········································································18 2.2 实验主要仪器········································································19 第三章 目标分子的合成····································································21 3.1 烷基取代二氯硅烷单体的合成 ···················································21 3.2 烷基取代聚硅烷化合物的合成 ···················································25 3.3 烷基取代聚硅烷化合物PSi1 、PSi2 和PSi3 圆二色谱及荧光光谱表征··28 第四章 非手性聚硅烷在机械涡流搅拌下的手性转移与传递行为 ··················31 4.1 研究背景··············································································31 4.2 实验部分··············································································31 4.3 结果与讨论············································································32 4.4 小结····················································································41 第五章 烷基取代聚硅烷分子内和分子间的手性传递行为···························42 5.1 烷基取代聚硅烷共聚物中―军官-士兵‖效应的研究···························42 5.2 烷基取代聚硅烷分子间及手性醇的手性传递行为研究······················46 第六章 工作总结与展望 ····································································54 参考文献·························································································55 攻读学位期间发表的文章 ·································································