SPE复合膜电极电解发生臭氧的性能.pdfVIP

学兔兔 化 工 进 展 ·914· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2010年第29卷第5期 PbO2／SPE复合膜电极电解发生臭氧的性能 陈俏微，赵峰鸣，马淳安 (浙江工业大学化学工程与材料学院，浙江 杭州 3 10032) 摘 要：采用化学镀法在Nation膜上直接沉积制备了PbO2／SPE复合膜电极，结合XRD、SEM分析了复合膜电 极上沉积层的晶相结构和形貌特征。结果表明，膜上沉积层为单一的四方结构13型PbO2，且其在Nation膜上沉 积致密，颗粒均匀，尺寸范围为300~500 am 通过恒电流电解实验研究了B—PbO2／SPE复合膜电极电解发生臭 氧的性能。结果表明，~-PbO2／SPE复合膜电极相比于其它两种膜电极更适合作为电解发生臭氧的阳极材料，在 所测试的电流密度范围内，当i=1．5 A／cm 时，臭氧产量达到最高为49．64 mg／h，电流效率l4．1％，槽压4．33 v， 能耗 102．7W·h／(gO3)。 关键词：二氧化铅；复合膜电极；臭氧；电解 中图分类号：O 646 文献标识码：A 文章编号：1000—6613(2010)05—0914—05 Electrolytic ozone properties of PbO2／SPE composite membrane electrode CHEN Qiaowei，ZHA0 Fengming，MA Chun’an (College ofChemical Engineering and Materials Science，Zh~iang University ofTechnology， Hangzhou 310032，Zhejiang，China) Abstract：PbO2／SPE composite membrane electrode was prepared by electroless plating directly deposited on Nation membrane．The crystalline structure and morphology were analyzed by XRD and SEM．Results showed that the deposited layer on the membrane has a single tetragonal~-PbO2 with homogenous and dense structure and particle size of about 300--500 am．The anodic oxygen evolution characteristic and electrolytic ozone properties of the prepared~-PbO2／SPE composite membrane electrode was investigated by using Galvanostat experiments．Compared to the other two membrane electrodes，the I3-PbOffSPE membrane electrode is more suitable as anode material for electrolytic