ZSM-5／MCM-48复合分子筛基催化剂上甲醇制汽油反应工艺条件的研究.pdfVIP

学兔兔 石 油 化 工 · 630· PETROCHEMICAL TECHN0L0GY 2012年第41卷第6期 ZSM一5／MCM一48复合分子筛基催化剂上 甲醇制汽油反应工艺条件的研究 李建青，焦雪静，狄佐星，宋建军，杨 成，吴晋沪 (中国科学院 青岛生物能源与过程研究所生物燃料重点实验室，山东 青岛266101) [关键词]ZSM一5／MCM一48复合分子筛基催化剂；甲醇制汽油；液体燃料 [文章编号]1000—8144(2012)06—0630—03 [中图分类号]TQ 426．64 [文献标识码]A Study on the Reaction Conditions of Methanol to Gasoline on ZSM一5／MCM一48 Based Catalyst LiJianqing，JiaoXuejing，DiZuoxing， Jianj“ ， Cheng，WuJinhu (KeyLaboratoryofBiofuels，QingdaoInstitute ofBioenergy andBioprocessTechnology，ChineseAcademyofSciences Qingdao Shandong 266101，China) l Abstract J The effects 0f reaction temperature，pressure and WHSV on the performance of ZSM一5／MCM一48 composite molecular sieve catalyst in methanol to gasoline(MTG、process were investigated，and was compared to ZSM．5 catalyst．It was found that the ZSM一5／MCM一48 catalyst was excellent for MTG，the content of aromatics in the liquid products was lowered effectively． and especially the durene content was reduced to 2％(w)or less．Under the appropriate reaction conditions：380—400 cC，0．5 MPa and WHSV 2 h- ，the conversion of methano1，the yield of C：， the mass fraction of aromatics and the mass fraction of durene in the liquid products were 99-3％． 33．7％，44_3％ and 1．7％，respectively． 1 Keywords]zSM一5／MCM一48 composite molecular sieve；methanol to gasoline；liquid fuel 甲醇转化为烃类液体燃料和化学品是当前替 1 实验部分 代石油技术研究的热点之一。早期由Mobil公司首 先提出了甲醇制汽油(MTG)技术。ZSM一5分子筛 ZSM一5／MCM一48复合分子筛的合成：四丙基 以其独特的孔道结构在MTG反应中表现出良好的