微生物代谢产物对膜生物反应器膜污染的影响.pdfVIP

学兔兔 化 工 进 展 2009年第28卷第8期 C旺 MICAL INDUSTRY AND ENGINEERING PROGRESS ·1473· 微生物代谢产物对膜生物反应器膜污染的影响 赵 军 ，张海丰 ，王 亮 ( 东北电力大学化学工程学院，吉林 吉林 132012； 天津工业大学材化学院环境工程系，天津 3001602) 摘 要：针对膜生物反应器(MBR)在运行过程中溶解性微生物代谢产物 (SMP)及胞外聚合物 (EPS)对膜污 染进行研究。实验过程中对MBR内的污泥混合液进行了定期膜阻力监测。结果表明，SMP和EPS对膜过滤阻力 有负面的影响。SMP中相对分子质量分布( )在3～10 kDa对膜内部阻力影响显著，SMP中 10 kDa的大 分子有机物及EPS浓度对膜外部阻力影响明显。通过傅里叶转换红外光谱 (FHR)检测膜表面污染物表明，EPS 主要由多聚糖、蛋白质和腐殖酸组成，而污染层中的SMP主要是多聚糖和腐殖酸 关键词：膜生物反应器；溶解性微生物代谢产物；胞外聚合物；膜污染 中图分类号：X 703．5 文献标识码：A 文章编号：1000—6613(2009)08—1473—06 Impact of microorganism metabolites on membrane fouling in membrane bioreactor ZHA0 Jun ，ZHANG Haifeng ，WANG Liang (1School of Chemistry Engineering，Northeast Dianli University，Jilin 132012，Jilin，China： Department of Environmental Engineering，Polytechnic Tianjin University，Tianjin 300160，China) Abstract：The influence of microorganism metabolites，such as soluble microbial products(SMP)and extracellular polymeric substances(EPS)，on membrane fouling was examined during the operation of membrane bioreactor(MBR)．The activated sludge samples were taken from a laboratory—scale MBR and used to investigate their fil~ation resistance in different phases．Results showed that the accumulated SNIP and EPS in the MBR have a negative effect on membrane filtration．Th e SMP，especially those with molecular weight(Mw1 of 3—10 kDa，are positively correlated to the pore—blocking resistance．The cake layer formation is the main factor resulting in membrane fouling，and is strongly affacted by the amount of EPS and the S 【I)with rw1