Experimental Assessment of the Sensitiveness of an Electrochemical Oscillator towards Chemical Perturbations 英文参考文献.docVIP

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Experimental Assessment of the Sensitiveness of an Electrochemical Oscillator towards Chemical Perturbations 英文参考文献.doc

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Experimental Assessment of the Sensitiveness of an Electrochemical Oscillator towards Chemical Perturbations 英文参考文献

ExperimentalAssessmentoftheSensitivenessofan ElectrochemicalOscillatortowardsChemical Perturbations GrazielaC.A.Ferreira1,BrunoC.Batista1,HamiltonVarela1,2* 1InstituteofChemistryofSa?o Carlos,UniversityofSa?o Paulo,Sa?o Carlos,Sa?o Paulo,Brazil,2ErtlCenterforElectrochemistryandCatalysis,GwangjuInstituteofScience andTechnology,Gwangju,SouthKorea Abstract Inthisstudyweaddresstheproblemoftheresponseofa(electro)chemicaloscillatortowardschemicalperturbationsof differentmagnitudes.Thechemicalperturbationwasachievedbyadditionofdistinctamountsoftrifluoromethanesulfonate (TFMSA),aratherstableandnon-specificallyadsorbinganion,andthesystemunderinvestigationwasthemethanolelectro- oxidationreactionunderbothstationaryandoscillatoryregimes.Increasingtheanionconcentrationresultedinadecrease inthereactionratesofmethanoloxidationandageneraldecreaseintheparameterwindowwhereoscillationsoccurred. Furthermore,theadditionofTFMSAwasfoundtodecreasetheinductionperiodandthetotaldurationofoscillations.The mechanism underlying these observations was derived mathematically and revealed that inhibition in the methanol oxidationthroughblockageofactivesiteswasfoundtofurtheracceleratetheintrinsicnon-stationarityoftheunperturbed system.Altogether,thepresentedresultsareamongthefewconcerningtheexperimentalassessmentofthesensitiveness ofanoscillatortowardschemicalperturbations.Theuniversalnatureofthecomplexchemicaloscillatorinvestigatedhere might be used for reference when studying the dynamics of other less accessible perturbed networks of (bio)chemical reactions. Citation: Ferreira GCA, Batista BC, Varela H (2012) Experimental Assessment of the Sensitiveness of an Electrochemical Oscillator towards Chemical Perturbations.PLoSONE7(11):e50145.doi:10.1371/journal.pone.0050145 Editor:BardErmentrout,UniversityofPittsburgh,UnitedStatesofAmerica ReceivedAugust23,2012;AcceptedOctober17,2012;PublishedNovember21,2012 Copyright: ? 2012 Ferreira etal. This is an open-access article distributed under the term