Preparation of Arylthiocyanates Using N,N′-Dibromo-N,N′-bis(2,5-dimethylbenzenesulphonyl) ethylenediamine and N,NDibromo-2,5-dimethylbenzenesulphonamide in the Presence of KSCN as a Novel Thiocyanating Reagent 英文参考文献.docVIP

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Preparation of Arylthiocyanates Using N,N′-Dibromo-N,N′-bis(2,5-dimethylbenzenesulphonyl) ethylenediamine and N,NDibromo-2,5-dimethylbenzenesulphonamide in the Presence of KSCN as a Novel Thiocyanating Reagent 英文参考文献.doc

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Preparation of Arylthiocyanates Using N,N′-Dibromo-N,N′-bis(2,5-dimethylbenzenesulphonyl) ethylenediamine and N,NDibromo-2,5-dimethylbenzenesulphonamide in the Presence of KSCN as a Novel Thiocyanating Reagent 英文参考文献

Molecules 2001, 6, 253–257 molecules ISSN 1420-3049 Preparation of Arylthiocyanates Using N,N′-Dibromo-N,N′- bis(2,5-dimethylbenzenesulphonyl) ethylenediamine and N,N- Dibromo-2,5-dimethylbenzenesulphonamide in the Presence of KSCN as a Novel Thiocyanating Reagent Ardeshir Khazaei*, Abdolhamid Alizadeh and Ramin Ghorbani Vaghei Department of Chemistry, Faculty of Science, Bu-Ali-Sina University, PIN-65175, Hamadan, Iran * Author to whom correspondence should be addressed; e-mail a_khazaei@basu.ac.ir Received: 3 December 2000; in revised form 29 December 2000 / Accepted: 12 December 2000 / Published: 28 February 2001 Abstract: N-Bromosulphonamides, synthesized via direct bromination of sulphonamides, react with several types of arene substrates in the presence of KSCN to afford aryl thiocyanates. The method appears to be generally applicable to benzenoid substrates with a wide range of substituents, such as N,N-dimethylaniline, p-xylene, anisole, mesitylene and cumene. Keywords: KSCN, novel thiocyanation, reagents, synthesis Introduction Direct introduction of sulfur into aromatic rings is an interesting objective. Two general strategies are commonly utilized for this purpose: sulfonation and thiocyanation. Though the latter would be more useful for our purpose, electrophilic thiocyanation methods described so far are often limited in scope [1], their main disadvantages being that the reagents used are either highly toxic or present serious disposal problems (or both). Molecules 2001, 6 254 The rather unstable thiocyanogen, (SCN)2, has often been used, generated usually in situ from copper or lead thiocyanates [2-4] or from molecular bromine and an alkali metal thiocyanate [1a]. Procedures involving the somewhat more reactive thiocyanogen chloride or iodide, XSCN, have also been described [3,5]. These methods call for the use of molecular halogen as co-reagent, or call for other sources