Silver Solid Amalgam Electrodes as Sensors for Chemical Carcinogens 英文参考文献.docVIP

Sensors 2006, 6, 445-452 sensors ISSN 1424-8220 ? 2006 by MDPI /sensors Silver Solid Amalgam Electrodes as Sensors for Chemical Carcinogens Jiri Barek , Jan Fischer ,Tomas Navratil , Karolina Peckova and Bogdan Yosypchuk 1,* 1 2 1 2 1 2 * UNESCO Laboratory of Environmental Electrochemistry, Department of Analytical Chemistry, Charles University, 128 43 Prague 2, Czech Republic J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejskova 3, 182 23 Prague 8, Czech Republic Author to whom correspondence should be addressed. E-mail: barek@natur.cuni.cz Received: 30 August 2005 / Accepted: 4 January 2006 / Published: 7 April 2006 Abstract: The applicability of differential pulse voltammetry (DPV) and adsorptive stripping voltammetry (AdSV) at a non-toxic meniscus-modified silver solid amalgam electrode (m-AgSAE) for the determination of trace amounts of genotoxic substances was demonstrated on the determination of micromolar and submicromolar concentrations of 3-nitrofluoranthene using methanol - 0.01 mol L NaOH (9:1) mixture as a base electrolyte -1 and of Ostazine Orange using 0.01 mol L NaOH as a base electrolyte. -1 Keywords: Solid amalgam electrodes, voltammetry, carcinogens, 3-nitrofluoranthene, Ostazine Orange.  Sensors 2006, 6 446 Introduction Ethical, social, and economic consequences of various forms of cancer raise carcinogenic substances monitoring in general and working environment to the highest priority [1,2]. Moreover, the determination of chemical carcinogens is an interesting challenge to any analyst, because it is necessary to determine extremely low concentrations of those substances in rather complex biological or environmental matr