Transformation of meta-stable calcium silicate hydrates to tobermorite reaction kinetics and molecular structure from XRD and NMR spectroscopy 英文参考文献.docVIP

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Transformation of meta-stable calcium silicate hydrates to tobermorite reaction kinetics and molecular structure from XRD and NMR spectroscopy 英文参考文献.doc

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Transformation of meta-stable calcium silicate hydrates to tobermorite reaction kinetics and molecular structure from XRD and NMR spectroscopy 英文参考文献

Geochemical Transactions BioMedCentral Research article Open Access Transformation of meta-stable calcium silicate hydrates to tobermorite: reaction kinetics and molecular structure from XRD and NMR spectroscopy Jacqueline R Houston*, Robert S Maxwell and Susan A Carroll Address: Chemistry, Materials, Earth, and Life Sciences Directorate; Lawrence Livermore National Laboratory, Livermore, CA 94550, USA Email: Jacqueline R Houston* - houston23@; Robert S Maxwell - maxwell7@; Susan A Carroll - carroll6@ * Corresponding author Published: 1 4 January 2009 Received: 1 7 October 2008 Accepted: 1 4 January 2009 Geochemical Transactions 2009, 10:1 doi:1 0.1 1 8 6/1 467-48 66-1 0-1 This article is available from: /content/1 0/1 /1 ? 2009 Houston et al; licensee BioMed Central Ltd. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Abstract Understanding the integrity of well-bore systems that are lined with Portland-based cements is critical to the successful storage of sequestered CO2 in gas and oil reservoirs. As a first step, we investigate reaction rates and mechanistic pathways for cement mineral growth in the absence of CO2 by coupling water chemistry with XRD and NMR spectroscopic data. We find that semi- crystalline calcium (alumino-)silicate hydrate (Al-CSH) forms as a precursor solid to the cement mineral tobermorite. Rate constants for tobermorite growth were found to be k = 0.6 (± 0.1 ) × 1 0-5 s-1 for a solution:solid of 1 0:1 and 1 .6 (± 0.8 ) × 1 0-4 s-1 for a solution:solid of 5:1 (batch mode; T = 1 50°C). This data indicates that reaction rates for tobermorite growth are faster when the solution volume is reduced by half, suggesting that rates are dependent on solution saturation and that the Gibbs