Transformation of meta-stable calcium silicate hydrates to tobermorite reaction kinetics and molecular structure from XRD and NMR spectroscopy 英文参考文献.docVIP
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Transformation of meta-stable calcium silicate hydrates to tobermorite reaction kinetics and molecular structure from XRD and NMR spectroscopy 英文参考文献
Geochemical Transactions
BioMedCentral
Research article
Open Access
Transformation of meta-stable calcium silicate hydrates to
tobermorite: reaction kinetics and molecular structure from XRD
and NMR spectroscopy
Jacqueline R Houston*, Robert S Maxwell and Susan A Carroll
Address: Chemistry, Materials, Earth, and Life Sciences Directorate; Lawrence Livermore National Laboratory, Livermore, CA 94550, USA
Email: Jacqueline R Houston* - houston23@; Robert S Maxwell - maxwell7@; Susan A Carroll - carroll6@
* Corresponding author
Published: 1 4 January 2009
Received: 1 7 October 2008
Accepted: 1 4 January 2009
Geochemical Transactions 2009, 10:1 doi:1 0.1 1 8 6/1 467-48 66-1 0-1
This article is available from: /content/1 0/1 /1
? 2009 Houston et al; licensee BioMed Central Ltd.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License (/licenses/by/2.0),
which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract
Understanding the integrity of well-bore systems that are lined with Portland-based cements is
critical to the successful storage of sequestered CO2 in gas and oil reservoirs. As a first step, we
investigate reaction rates and mechanistic pathways for cement mineral growth in the absence of
CO2 by coupling water chemistry with XRD and NMR spectroscopic data. We find that semi-
crystalline calcium (alumino-)silicate hydrate (Al-CSH) forms as a precursor solid to the cement
mineral tobermorite. Rate constants for tobermorite growth were found to be k = 0.6 (± 0.1 ) ×
1 0-5 s-1 for a solution:solid of 1 0:1 and 1 .6 (± 0.8 ) × 1 0-4 s-1 for a solution:solid of 5:1 (batch mode;
T = 1 50°C). This data indicates that reaction rates for tobermorite growth are faster when the
solution volume is reduced by half, suggesting that rates are dependent on solution saturation and
that the Gibbs
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