CO2在地层水中溶解度实验及理论研究+本科生校优.docVIP

CO2在地层水中溶解度实验及理论研究 石油工程学院 专业年级：石油工程2009级 指导教师：卞小强 摘 要CO2在深部咸水层中埋存是减轻温室效应的有效途径之一，由于CO2具有超临界特性，CO2在地层水中的溶解能力远大于常规烃类气体，目前超临界CO2在不同矿化度的地层水中溶解规律仍没有完全认识清楚。针对此问题，采用物理模拟和理论模型相结合的研究方法，通过平衡液体闪蒸实验，测定不同温度不同压力条件下CO2在不同矿化度以及不同离子含量地层水中的溶解度。结果表明：在实验温度压力条件下，CO2在地层水中溶解度在11.83~37.31m3/m3之间；温度越高，CO2的溶解度越低，低压下随温度增加CO2溶解度降低幅度比高压下大；压力越高，CO2的溶解度越大，低温下随压力增加CO2溶解度增加的幅度比高温下小。对比6种CO2溶解度计算模型（Chang、Furnival、PR-HV、Duan(2003)、Duan(2006)、Dubacq）和实验数据表明：Duan(2006)模型精度最高（AAD=2.77%），其次是Duan(2003)模型（AAD=3.27%），最差的是Chang模型（AAD=10.24%）。该研究为准确快速求取CO2在地层水中溶解度数据提供新方法，对阐明CO2在深部咸水层有效埋存中的溶解机理具有重要意义。 关键词：CO2；溶解度；实验；理论模型；平均相对误差 Abstract：The storage of CO2 in deep saline aquifers is one of the effective methods to reduce the greenhouse effect. Due to the characteristics of supercritical CO2，the solubility of CO2 in the formation water is greater than that of hydrocarbon gas reservoir. It is incompletely clear that the supercritical CO2 dissolves in formation water with different salinity at present. When it comes to this question, a combination of experiment and numerical models was adopted. The solubility of CO2 in formation water with different salinities and different ion concentration was measured at different pressure and temperature conditions through balance liquid flash test. The results show that the solubility of CO2 in formation water varies from 11.83 to 37.31 m3/m3 at the range of experiments, that the CO2 solubility decreases with increasing temperature and the increase of the CO2 solubility with increasing temperature at lower pressure is greater than that at higher pressure, and that the CO2 solubility increases with increasing pressure and the increase of the CO2 solubility with increasing pressure at lower temperature is less than that at higher temperature. A comparison of 6 models (Chang, Furnival, PR-HV, Duan (2003), Duan (2006) and Dubacq model) of CO2 solubility in formation water and experimental data shows that the accuracy of Duan (2006) model is the highest among all models in this