液相沉积制备TiO2／Al颜料及其在自清洁涂料中的应用.pdfVIP

学兔兔 第15卷第3期 粉末冶金材料科学与工程 2010年6月 Vbl_15 NO．3 Materials Science and Engineering of Powder Metallurgy Jun 2O10 液相沉积制备TiO2／Al颜料及其在自清洁涂料中的应用 蒯 勤，叶红齐，高 莹 (中南大学 化学化工学院，长沙 410083) 摘 要：以硫酸氧钛和氢氧化钠为主要原料，采用液相沉积法在片状Al粉表面包覆TiO2，制备TiO2／Al颜料，并 进一步制得含有该颜料的白清洁涂料。以油酸为污染模拟物，用油酸的分解率作为评价手段，考察反应 pH、煅 烧温度、涂膜厚度对该涂料白清洁性能的影响。通过XRD仪对颜料结构进行表征，并对颜料的分散性和耐腐蚀 性能进行研究。结果表明：在pH为4．5、煅烧温度为600℃条件下TiO2／Al表面的TiO2晶型为锐钛矿型，因而具 有最强的自清洁能力。当颜料涂膜厚75 um时，经紫外灯光照3 h后油酸的分解率达到91％。用752S型可见分 光光度计于2=420 am处分别测得Al粉和TiO2／A1颜料的透光率，来表征其分散性，结果证明Al粉的透光率比 TiO2／A1高30％；用浓度0．1 mol／L的HC1溶液进行腐蚀实验，TiO2／Al颜料的耐腐蚀性能显著提高。 关键词：Al粉；TiO，／A1；液相沉积；光催化；自清洁涂料 中图分类号：TF123．7 文献标识码：A 文章编号：1673．0224(2010)3．283．05 Preparation of aluminum titanium pigments and its application in self-cleaning coating KUAI Qin，YE Hong—qi，GAO Ying (School ofChemistry and Chemical Engineering，Central South university,Changsha 410083，China) Abstract：Self-cleaning TiO2／Al pigments was prepared through liquid deposition，using TiOSO4，NaOH as main materials，then the self-cleaning coating containing TiOz／A1 pigments was prepared．Through using oleic acid as simulacrum，the degradation rate of oleic acid as evaluation measure，self-cleaning properties of TiO2／A1 coating prepared at different conditions were investigated．Structure of pigm ents was characterized by XRD，and the dispersity and corrosion resistance were also studied．The results show that when pH value is 4．5，calcining temperature reaches 600℃， the TiO2 on the surface of TiO2／A1 powder exhibits as