轮胎氧化.pptVIP

The aging of rubber caused by oxidative degradation leads to the deterioration in the physical and mechanical properties of vulcanized rubbers. The critical review will cover the major develop-ments in our understanding of the oxidation of rubbers. The mechanisms relative to oxidation of rubber Methods of protection The mechanisms relative to oxidation of rubber Polymer degradation is caused by chemical bond scission reactions in macromolecules.The initiation modes of chemical degradation include thermal, mechanical,photochemical,radiation chemical, biological and chemical degradation of polymetric materials. In addition,we ofen find the aging phenomenon of white, cracked surface , the deterioration of physical and mechanical properties in the process of rubber products used. The mechanisms relative to oxidation of rubber R?+O2→RO2? (1) RO2?+RH→ROOH+R? (2) ROOH→RO?+?OH (3) RO?+RH→ROH+R? (4) RH+?OH→H2O+R? (5) RO2?+RO2?→ROOR(stable)+O2 (6) The mechanisms relative to oxidation of rubber the loss of unsaturation of α,β-unsaturated oxidized products through crosslinking: x-CH=CH-CH2- x-CH-CH-CH2- → ? ? -CH2-CH=CH-CH2- -CH2-CH-CH-CH2- with:x=-C-, -C-OH, -C-, -C-H ? ?? ?? ?? OH O O O The mechanisms relative to oxidation of rubber the formation of an ether linkage through photooxidation: CH3 CH3 ? ? ?C=C -CH-CH=C-CH2- → -CH-CH=C-CH2- ------→ ? ? +H? OOH O? CH3 ? -CH-CH=C-CH2- ? O ? -C-CH- ? ? Methods of protection Ozo