物化实验 旋光物质化学反应反应动力学研究.pdfVIP

USTC 鐗╃悊鍖栧瀹為獙鎶ュ憡 瀹為獙涓 鏃嬪厜鐗╄川鍖栧鍙嶅簲鍙嶅簲鍔ㄥ姏瀛︾爺 绌 EXPERIMENT 7 锛歍he Study of Chemistry Reaction Dynamics Via Optical Rotation 寮犱粯鐟 P 鍖栧涓庢潗鏂欑瀛﹀闄 鏉愭枡绉戝涓庡伐绋嬬郴 Department of Materials Science Engineering锛孲chool of Chemistry and Materials Science USTC 鐗╃悊鍖栧 瀹為獙鎶ュ憡 2013 骞寸浜屽鏈熷疄楠屾姤鍛 USTC 鏉愭枡绉戝涓庡伐绋嬬郴 寮犱粯鐟 P 椤 0 USTC 鐗╃悊鍖栧瀹為獙鎶ュ憡 鏃嬪厜鐗╄川鍖栧鍙嶅簲鍔ㄥ姏瀛︾爺绌 路鎽樿锛 鏈疄楠屼富瑕侀€氳繃鐗╃悊鏂规硶娴嬪畾钄楃硸鍙嶅簲杩囩▼涓殑娴撳害鍙樺寲锛屼篃 灏辨槸鍒╃敤鍙嶅簲鐗╁拰浜х墿鐨勬棆鍏夊害涓嶅悓鑰屽紩璧风殑鐩稿簲鐨勬棆鍏夊害鍙 鍖栥€備粠鑰岀爺绌跺叾鍙嶅簲鐨勫姩鍔涘瑙勫緥锛屽寘鎷笉鍚屾俯搴︿笅鐨勫弽搴旈€熺巼 甯告暟锛屾椿鍖栬兘鐨勮绠楃瓑銆傚苟涓旀祴閲忚繃绋嬩负鍘熶綅娴嬮噺锛屽鍙嶅簲浣撶郴 鐨勫奖鍝嶈緝灏忋€傛湰瀹為獙浣滀负鍖栧鍙嶅簲鍔ㄥ姏瀛﹀熀纭€鎬у疄楠屾槸闈炲父鍏稿瀷 鑰屾湁娣辫繙鎰忎箟鐨勩€ 路鍏抽敭璇嶏細 鏃嬪厜鐜囷紱钄楃硸鍒嗚В鍙嶅簲锛涘寲瀛﹀弽搴斿姩鍔涘锛涘噯涓€绾у弽搴旓紱鍖栧鍙 搴旈€熺巼甯告暟锛涙椿鍖栬兘 路Abstract锛 This experiment measure the concentration change of sucrose via physical method, in other words, this change is an specific rotation change caused by the difference of reactants between products. So that we can study the reaction鈥檚 chemical dynamics rules, including reaction rate constants of different temperature and activation energy, etc. Also the measure method in this experiment is a kind of in-situ measurement, which can reduce the influence to the reaction system. In short, as a fundamental teaching experiment, this experiment is a very representative and influential. USTC 鐗╃悊鍖栧瀹為獙鎶ュ憡 鏃嬪厜鐗╄川鍖栧鍙嶅簲鍔ㄥ姏瀛︾爺绌 路Keyword: optical rotation rate; decomposition reaction of sucrose; dynamics of chemical reaction; pseudo-firs