高温高压酚化木质素改性酚醛泡沫性能.pdfVIP

学兔兔 中国科技核心期刊 新 毒蟓 高温高压酚化木质素改牲酚醛泡沫性链 姜晓文 ，刁桂芝 ，王娟 ，赵彤 (1．中国科学院化学研究所，北京 l0o190； 2．中国建筑材料科学研究总院，北京 100024) 摘要：采用场解吸质谱(FieId Desorption—Mass Spectroscopy，FD—MS)表征了玉米芯木质素、麦秆木质素和混合木质素(玉米芯、 秸秆等的混合物)3种不同木质素的结构；以磷酸为催化剂，在高温高压条件下用苯酚对木质素进行酚化改性，用FD—MS对木质素 的酚化反应进行了研究。结果表明，FD—MS可以直观得到木质素各组分的分子质量及分子质量分布，木质素经酚化反应后分子质量 减小，多分散系数减小，木质素中各个组分均参与了酚化反应，其中玉米芯木质素的酚化效果最好，经酚化反应后生成大量双酚F 及其衍生物，酚化木质素具有与热塑性酚醛树脂相似的结构，采用该酚化木质素改性酚醛树脂发泡，制备的酚醛泡沫细腻，且韧性有 明显提高。 关键词：木质素；酚化；酚醛泡沫；场解吸质谱(FD—MS) 中图分类号：TUI_11．4+1；TU55 文献标识码：A 文章编号：1001—702X(2014)09—0070—05 Phenoltion lignin under high temperature-pressure modified phenolic resin and phenolic foam properties J／ANG Xiaowen ，DIA0 Guizhi ，WANG Juan ，ZHA0 To (1．Institute of Chemistry，Chinese Academy of Sciences，Beijing 100190，China； ’ 2．China Building Materials Academy，Beijing 100024，China) Abstract：The structures of three kinds of lignins (corn—cob lignin，wheat straw lignin and mixed lignin)were characterized by field desorption．mass spectroscopy(FD-MS)．These lignins were phenolated using phenol as the medium and phosphoric acid as the catalyst under hish temperature-pressure condition．Th en the three phenolated lignins were also measured by FD—MS．The results showed that FD—MS Call be used directly for studying molecular weisat and molecular weight distributions of lignins．After the phenolation，both the molecular weight and distribution of lignin decreased．All parts of lignin reacted with phenol during the pheno