固体废弃物低温烧制优等节能保温砖强度机理及热性能分析.docVIP

第2卷第4期 环境工程学报 V。1．2，N。．4 』二竺皇：!!：竺兰旦 ￡!!里曼!皇!竺旦婴璺!竺!垦旦!i!竺翌竺!翌堕!垦里曼i!旦!巫翌曼 垒旦!：三旦!! 固体废弃物低温烧制优等节能保温砖 强度机理及热性能分析 徐子芳 张明旭 闵凡飞 (安徽理工大学材料科学与工程学院，淮南232001) 摘 要 采用废弃物粉煤灰和煤矸石为主要原料焙烧实心墙体保温砖。正交实验优化结果为：焙烧温度950 oC，低于 实心粘土砖100℃的焙烧温度，属于低温焙烧。焙烧周期24 h，粉煤灰和煤矸石的掺量比是60％：35％，掺膨胀珍珠岩的保 温砖B7抗压强度为30．25 MPa，达到普通粘土砖MU30优等级；导热系数为0．400 W／(ni· K)，低于普通粘土砖的导热系 数0．78 W／(m· K)；此外，B7的XRD图谱出现明显的石英、莫来石衍射特征峰及TGA— DTA图谱在900一l 200℃的区间， 随着温度的升高，坯体吸热开始熔融玻化，产生晶型转变，使力学性能得到提高；SEM扫描可见：经950℃焙烧后，球体状的 实心玻璃珠、珠状皱晶的珍珠岩、絮凝状的铝硅酸盐相，原料颗粒之间的间隙被粘性玻璃质所填充，使B7产生很高的力学 强度。 关键词 固体废弃物焙烧 保温砖 性能分析 中图分类号X705 文献标识码 A 文章编号1673-9108(2008)04-0548-05 Thermal performance and strength mechanism analysis of using solid waste at low temperature to roast high．class heat insulation brick Xu Zifang Zhang Mingxu Min Fanfei (School of Material Science and Engineering，Anhui University of Science and Technology，Huainan 232001) Abstract Fly ash and coal gangue were used as main raw materials to roast solid insulating brick．Cross experiment optimization results show that when roasting temperature is 950 oC(10wer than solid clay brick 1 00 ℃，belong 10 low temperature roasting)，roasting time cycle is 24 h，fly ash and coal gangue scale is 60％： 35％，the B7 admixing expanded pearlite compressive strength is 30．25 MPa．Strength rcach general clay brick MU30 high-class level．Thermal coefficient of conduction is 0．4 W／(m· K)，lower than general clay brick ther— mal coefficient of conduction 0．78 W／(m· K)．In addition，B7 XRD pattern has evident quartz、mullite dif- fraction character peak and TGA-DTA pattern between 900— 1 200℃，following temperature rise，green body heat— absorbing，begin melt，glass reduction．The result is high in strengths．SEM scanning shows that after be roasted at 950 oC，globular solid glass bead，pearlitic drusy pearlite，flocculation aluminosilicate phase and SO on， raw materials particle interstices are filled with viscous hyaline，SO that B7 turns out high strengths． Key words solid waste；roasting；insulating brick；performance analysis 长期以来，粘土实