二氧化钛颗粒表面的光催化反应过程-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2012年第41卷第2期 PETR0CHEMICAL TECHN0L0GY ·219· ■ 评 二氧化钛颗粒表面的光催化反应过程 韦冰心，王亭杰，赵 琳，陈 林，金 涌 (清华大学 化工系，北京 100084) [摘要]综述了TiO：颗粒表面光催化反应过程的研究进展。以电子空穴机理为主线，结合最新研究结果，分析了电子空穴机 理的具体反应历程。并按照光生电子空穴分离、自由基产生和自由基氧化3个过程分析了TiO 颗粒表面光催化反应历程，重点 分析了自由基产生过程，明确TTi 和0；等基团的形成过程和在光催化反应过程中的作用。基于TiO 光催化反应历程，提出了 TiO 光催化活性的调控措施。通过提高电子和空穴复合几率，可抑制Ti0：的光催化活性；通过减小禁带宽度，或抑制电子和空 穴复合，可提高TiO，的光催化活性。 [关键词]二氧化钛；光催化；光生电子；光生空穴；自由基 [文章编号]1000—8144(2012)02—0219—05 [中图分类号]TQ 426 [文献标识码]A PhOtOcatalytic Reaction Process on Titania Particle Surface WeiBingxin，WangTingjie，ZhaoLin，ChenLin，Jin Yong (Department of Chemical Engineering，Tsinghua University，Beijing 100084，China) [Abstract]The photocatalyfic reaction process on titania particle surface and its research progress were analyzed．According to the electron—hole mechanism the detailed reaction process was summarized combining the newest research achievements，including the separation of the photoelectron and photohole，formation of the free radicals and oxidation of the free radicals．The form ation of Ti and 0i and their roles in the photocatalytic process were clarified．Based on the photocatalytic reaction mechanism，the control of TiO2 photocatalytic activity was elucidated systematically．The photocatalytic activity can be restricted by providing plenty recombination sites and increasing capture capability for photoelectrons and photoholes with a specially coated film．The activity can be increased by reducing the band gap or doping specific ions to form capture sites for restriction of the