溶胶-凝胶法制备苯基甲基二甲氧基硅烷改性聚乙烯醇缩丁醛涂层-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 304· PETROCHEMICAL TECHN0L0GY 2011年第40卷第3期 溶胶 一凝胶法制备苯基甲基二甲氧基硅烷改性 聚乙烯醇缩丁醛涂层 李照磊，高延敏，郑传波，朱静燕，刘坤鹏，吴欣凯 (江苏科技大学 材料科学与工程学院，江苏 镇江 212003) [摘要]为改善聚乙烯醇缩丁醛(PVB)涂层的耐温性和耐腐蚀性，以磷酸为催化剂、正硅酸乙酯(TEOS)为前体进行溶胶一凝胶 反应，用苯基甲基二甲氧基硅烷(PDMS)对PVB进行改性；并用FIIR、TG、XRD、SEM、极化和EIS等手段对改性前后的涂层进行 了表征。实验结果表明，改性PVB分子结构中的羟基完全与PDMS分子中的烷氧基发生反应；改性PVB涂层中有纳米级Si02填 料生成，SiO2在PVB涂层中的分散性良好，且粒径较均匀；改性PVB涂层的耐腐蚀性和耐温性均有所提高；与纯PVB涂层相比， 改性PVB涂层的阻抗值提高了3个数量级。 [关键词]溶胶一凝胶；聚乙烯醇缩丁醛；苯基甲基二甲氧基硅烷；耐温性；耐腐蚀性 [文章编号]1000—8144(2011)03—0304—05 [中图分类号]TQ 631．2 [文献标识码]A Phenylmethyldimethoxysilane Modified Polyvinyl Butyral Coating Prepared by Sol-Gel Method Li Zhaolei，Gao Yanmin，Zheng Chuanbo，Zhu Jingyan，Liu Kunpeng，Wu Xinkai (School of Material Science and Engineering，Jiangsu University of Science and Technology，Zhenjiang Jiangsu 212003，China) [Abstract]To improve its thermotolerance and corrosion resistance，polyvinyl butyral(PVB)coating was modified by phenylmethyldimethoxysilane(PDMS)through sol—gel method with phosphoric acid as the catalyst and tetraethyl orthosilicate(TEOS)as the precursor．PVB and the modified product were characterized by means of FHR，TG，XRD，SEM ，polarization and EIS methods．The results showed that hydroxyls in PVB molecules fully reacted with alkoxys in phenylmethyldimethoxysilane molecules．Si02 nano—particles generated and dispersed well with a uniform size in the modified PVB coating．Both the thermotolerance and the corrosion resistance of the modifi