溶胶-凝胶法制备氮掺杂Ti02的制备条件优化-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 PETR0CHEMICAL TECHN0L0GY 20l1年第40卷第9期 溶胶一凝胶法制备氮掺杂TiO2的制备条件优化 安兴才，韩立娟，陈作雁，喜文华 (甘肃省科学院 自然能源研究所，甘肃 兰州730046) [摘要]以二乙醇胺为氮源，乙酸为抑制剂，乙醇为溶剂，采用溶胶一凝胶法制备了氮掺杂TiO2。以苯酚为污染物，在模拟太阳光 (氙灯)下，考察了氮掺杂TiO，制备过程中水用量、乙酸用量、乙醇用量、二乙醇胺用量、陈化温度、煅烧温度和煅烧时间7个医i索 对氮掺杂TiO2光催化活性的影响，并采用正交实验优化了氮掺杂TiO2的制备条件。实验结果表明，煅烧温度对氮掺杂TiO2的光 催化活性具有非常显著的影响；最优的制备条件为：n(钛酸四丁酯)：n(水)：n(乙酸)：n(乙醇)：n(二乙醇胺)=1：462： 17．3：3：0．4(n(钛酸四丁酯)=0．015 mo1)，陈化温度为45℃，煅烧温度为400 oC，煅烧时间为4 h。在此条件下制备的氮掺杂 TiO2对苯酚光催化反应3 h，其降解率达到75．13％，是未掺杂氮TiO2的1．7倍。 [关键词]二氧化钛；氮掺杂；光催化；苯酚；降解 [文章编号]1000—8144(2011)09—1000—06 [中图分类号]TQ 428 [文献标识码]A Preparation of Nitrogen Doped TiO2 Powder by Sol-Gel Method An Xingcai，Han Lijuan，Chen Zuoyan，Xi Wenhua (Gansu Natural Energy Research Institute，GSAS，Lanzhou Gansu 730046，China) [Abstract]Nitrogen doped TiO2 powder was prepared by sol-gel method with diethanolamine as the nitrogen source，acetic acid as the inhibitor and absolute ethyl alcohol as the solvent．The influences of water dosage，acetic acid dosage，absolute ethyl alcohol dosage and diethanolamine dosage，aging temperature，calcination temperature and calcination time on the photocatalytic activity of the nitrogen doped TiO2 in phenol degradation under xenon lamp were investigated．The preparation conditions were optimized by using orthogonal design．The results showed that the effect of the calcination temperature on the photocatalytic activity of the nitrogen doped TiO2 was significant．The optimum