环氧乙烷异构化反应动力学的研究-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2011年第40卷第2期 PFⅡtOCHEMICAL TECHN0LOGY ·175· 环氧乙烷异构化反应动力学的研究 陈建设，代武军，崔宝林，孙向华，郇 毅，马德旺 (中国石化北京北化院燕山分院，北京102500) [摘要]采用Beny微反装置，在温度180～250℃、压力1．4～2．1 MPa的条件下，对氧化铝载体和银催化剂上的环氧乙烷异构化 反应进行了反应动力学实验。实验结果表明，环氧乙烷在氧化铝载体和银催化剂上均发生异构化反应生成乙醛；在氧化铝载体 上，异构化反应速率对环氧乙烷浓度的表观反应级数约为1，表观活化能为56．89 kJ／mol，指数前因子为9．646×10 ；在银催化剂 上，异构化反应速率对环氧乙烷浓度的表观反应级数约为0．8，表观活化能为61．42 kJ／mol，指数前因子为2．267×10 。 [关键词]环氧乙烷；银催化剂；氧化铝载体；异构化反应；乙醛；反应动力学 『文章编号]1000—8144(2011)02—0175—04 [中图分类号]TQ 013．2 [文献标识码]A Kinetics of Ethylene Oxide Isomerization Reaction Chen Jianshe，Dai Wujun，Cui Baolin，Sun Xianghua，Huan ，Ma Dewang (Yanshan Branch，SINOPEC BRICI，Beijing 102500，China) [Abstract]Isomerization of ethylene oxide(EO)to acetaldehyde was studied in a Berty mico—reactor in the temperature range of 180—250 oC and the pressure range of 1 ． 4—2．1]VIPa，which was a side reaction of ethylene epoxidation to EO． The isomerization reaction kinetics was investigated． The results indicated that：(1)over the alumina support，the apparent reaction order of EO concentration was about 1 and the apparent activation energy was 56．89 kJ／mo1．(2)over YS-7 silver catalyst，the apparent reaction order of EO concentration was about 0．8 and the apparent activation energy was 6 1．42 kJ／mo1．(3)the pre exponential factors of the EO isomerization reaction over YS一7 silver catalyst and the alumina support were 2．267×10 and 9．646×10 ．respectively． [Keywords]ethylene oxide；silver catalyst；alumina support；isomerization reaction；acetaldehyde； reaction kinetics