裂解C5分离中溶剂二甲基甲酰胺的再生工艺研究-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 Op 石 油 化 工 ～术一 ～技一 ～业一 一工一 PETROCHEMICAL TECHN0L0GY ·l269· 2010年第39卷第11期 3 裂解C5分离中溶剂二甲基甲酰胺的再生工艺研究 李晓峰，李东风，张礼昌 (中国石油化工股份有限公司 北京化工研究院，北京 100013) [摘要]针对裂解C 分离流程中Ⅳ，Ⅳ一二甲基甲酰胺(DMF)再生发生水解等问题，提出了一种新型的DMF再生方法，再生工艺 包括再生釜、减压精溜塔和反应精馏塔。采用Aspen Plus流程模拟软件对该再生工艺进行了模拟计算，计算结果表明，DMF再生 过程中有微量损失。在小型实验装置中分别进行了减压精馏实验和反应精馏实验。实验结果表明，减压精馏塔顶馏分中双环戊 二烯的质量分数为42 3％，塔釜液中DMF质量分数为99．8％，达到了DMF再生要求；反应精馏塔顶可得到高纯度环戊二烯，塔 釜液可循环返回再生釜。DMF再生工艺是可行的。 [关键词]裂解碳五；Ⅳ，Ⅳ一二甲基甲酰胺；双环戊二烯；减压精馏；反应精馏；溶剂再生 [文章编号]1000—8144(2010)11—1269—04 [中图分类号]TQ 028 [文献标识码]A Recovery of Solvent N，N-Dimethylformamide Used in Separation of Cracking Cs Fraction Li Xiaofeng，Li Dongfeng，Zhang Lichang (Beijing Research Institute of Chemical Industry，SINOPEC，Beijing 100013，China) [Abstract]In order to avoid hydrolysis of N，N-dimethylformamide(DMF)used as the solvent in the separation of cracking C5 fraction，a novel DMF recovery process was proposed，which included recovering kettle，vacuum distillation column and reactive distillation column． The process was simulated by means of Aspen Plus SOftware and the results indicated a mere trace of the DMF lOSS．The vacuum distillation and the reactive distillation were conducted separately in the separation experiment． The results of the vacuum distillation showed that the mass fraction of dicyc1opentadiene at the column top was 42．3％ and the mass fraction of DMF at the column bottom was 99．8％ ．which could meet the requirement of the recovery． The results of the reactive distillation indicated that high—purlty cvclopentadiene was obtmned at the column to