萃取精馏分离均三甲苯的实验和模拟-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2011年第40卷第2期 PETROCHEMICAL TECHN0L0GY ·157· 萃取精馏分离均三甲苯的实验和模拟 冯海强 ，傅吉全 (1．中国石化北京化工研究院，北京 100013；2．北京服装学院化工研究所，北京 100029) [摘要]对从C。芳烃中分离均三甲苯进行了萃取精馏实验，并采用Aspen Plus流程模拟软件对萃取精馏塔进行了模拟计算。考 察了回流比和溶剂比对分离均三甲苯的影响。实验结果表明，在理论塔板数为66块、回流比为20～25、萃取剂与进料的质量比为 8的条件下，萃取精馏塔塔顶馏出物中均三甲苯的摩尔分数( M s)为98．2％； 的计算值与实验值的平均绝对偏差，在塔顶小 于0．2％，在塔釜小于0．8％，在塔内液相小于2．0％，计算值与实验值吻合较好。建立的模拟方法可用于萃取精馏分离均三甲苯 工艺的计算。 [关键词]碳九芳烃；均三甲苯；萃取精馏；Aspen Plus流程模拟软件 [文章编号]1000—8144(2011)02—0157—04 [中图分类号]TQ 028 [文献标识码]A Experiment and Simulation of Separating Mesitylene by Extractive Distillation Feng Haiqiang ，Fu Jiquan (1．Beijing Research Institute of Chemical Industry，SINOPEC，Beijing 100013，China； 2．Center of Chemical Engineering，Beijing Institute of Clothing Technology，Beijing 100029，China) [Abstract]Separation of mesitylene from C9 arene was carried out by extractive distillation method and Aspen Plus SOftware was employed to simulate the extractive distillation tower．Efiects of reflUX ratio and solvent ratio on the mesitylene separation were investigated．Under the extractive distillation conditions of theoretical plate number 66，reflux ratio 20—25 and mass ratio of solvent to feed 8．mole fraction of mesitylene in overhead could reach 98．2％ ． The simulation results fitted well the experimental data．The mean absolute errors for mole fractions of mesitylene in overhead．bottom and liquid phase within the extractive distillation tower are less than 0．2％ ．0．8％ and 2．0％ ．respectively． It is considered that the established simulation method can be used in simulation