乙烯-醋酸乙烯共聚物丁苯橡胶热塑性硫化胶的压缩Mullins效应及其可逆回复.pdfVIP

第 37 卷第 l 期 青岛科技大学学报(自然科学版) Vo l. 37 No.1 2016 年 2 月 Journal of Qingdao University of Science and Technology(Natural Science Edition) Feb.2016 文章编号:1672-6987(2016)01-0056-06; 001: 10. 16351/j. 1672-6987.2016.01. 012 乙烯·醋酸乙烯共聚物/丁苯橡胶热塑性硫化胶的 压缩 Mullins 效应及其可逆回复 王灿灿，刘情情，王兆波幡 (青岛科技大学材料科学与工程学院，山东青岛 266042) 摘 要:采用动态硫化法制备了乙烯-醋酸乙烯共聚物CEVA)/丁苯橡胶(SBR) 热塑性硫 化胶CTPV) ，对其微观结构、压缩 Mullíns 效应及其可逆回复进行了研究。结果表明: TPV 在单轴循环压缩过程中存在显著的 Mullins 效应，在特定压缩应变下，最大压缩应 力、内耗及 tanδ 均在第一次循环压缩时出现最大佳，第二次压缩时显著降低，之后下降趋 势减缓;提高热处理混度，二次循环压缩的最大压缩的应力回复程度增大，且 80 C 热处理 时 Mullins 效应回复效果最佳。研究表明，SBR 硫化胶粒子以 3~8μm 的尺寸均匀分散 子刻蚀样品表岳。 关键词:乙烯-醋酸乙烯共聚物;丁苯橡胶;动态硫化;压缩 Mullins 效应;可逆回复 中图分类号: TQ 334.2; TQ 333. 1 文献标志码:A Mullins Effect Under Compression Mode and Its Reversibility of EVA/SBR Thermoplastic Vulcanizates WANG Can-can , LIU Qing-qing , WANG Zhao-bo (College of Materials Sciençe and Engineering , Qingdao Univ巳rsity of Science and Technology. Qingdao 266042. China) Abstract: Thermoplastic vulcanizates (TPV) based on ethylene-vinyl acetate copolymer CEVA) / styrene-butadiene rubber (SBR) blends were prepared by dynamic vulcaniza tion. The microstructure , Mullins effect under compression mode and its reversibility of the prepared TPV were investigated. Experimental results indicated that Mullins effect could be observed in the compression stress-strain curves of the TPV during the uniaxial loading-unloading cycles; and the maximum stress , internal friction loss and tana at spe- cific strain were decreased obviously aft巳r the first loading-unloading while only de creased slightly at the later loading-unloading cycles. The maximum