化学添加剂对水合物生成和储气的影响.pdfVIP

学兔兔 石 油 与 天 然 气 化 工 146 CHEMICAL ENGINEERING OF OIL GAS 2O14 化学添加剂对水合物生成和储气的影响 张庆东 李玉星 王武昌 (中国石油大学(华东)储运与建筑工程学院) 摘 要 为了研究促进剂对水合物生成的影响，采用自行设计的水合物反应系统，通过恒温定 容实验，研究了四氢呋喃(THF)和十二烷基硫酸钠(SDS)对二氧化碳水合物生成的影响。并在实 时测量水合物生成过程中系统的温度、压力的基础上，计算得出水合物的生成速率、储气量及表观 水合数。结果表明，适宜浓度的SDS能促进气体在液相的溶解，提高水合物的生长速率和储气密 度；单独添加THF对水合物生成过程促进效果并不明显；SDS和THF复合添加剂共同作用对水 合物促进效果最显著。 关键词 水合物 生成 添加剂 二氧化碳 储气量 中图分类号：TEa 文献标志码：A DOI：10．3969／j．issn．1007—3426．2014．02．008 Influence of chemical additives on hydrate formation and gas storage Zhang Qingdong，Li Yuxing，Wang Wuchang (College of Pipeline and Civil Engineering，China University of Petroleum， Qingdao 266580，Shandong，China) Abstract：In order to study effects of promoters on hydrate formation，adopting a self—de— signed hydrate reaction system，influences of the tetrahydrofuran(THF)and sodium dodecyl sulfate(SDS)on carbon dioxide hydrate formation were studied through experiments with con— stant temperature and volume．Hydrate formation rate，gas storage capacity and the apparent hy— dration number were calculated on the basis of real—time measurements of system temperature and pressure in the process of hydrate formation．The result showed that the suitable concentra— tion of SDS can promote the dissolution of gas in the liquid phase，and improve the growth rate and gas storage density of hydrate．THF only had little effect on hydrate generation process． Compound additives SDS and THF working together could promote the hydrate formation impor