MTBE选择性吸附脱硫的研究.pdfVIP

学兔兔 石 油 与 天 然 气 化 工 22 CHEMICA L ENGINEERING OF OIL GAS 2O15 MTBE选择性吸附脱硫的研究 卢衍楠 施 力 孟 璇 华东理工大学石油加工研究所 摘 要 采用常温常压吸附法考察了各种分子筛吸附剂对模型溶液中二甲基二硫醚(DMDS)的吸 附脱除性能。吸附活性结果表明，由于MTBE的强竞争吸附作用，仅ZSM一5分子筛可以从MTBE选 择性吸附脱除DMDS，而其他分子筛均完全没有效果。ZSM一5所特有的十元环孔道是选择性吸附的关 键。通过一系列过渡金属改性，结果显示，仅银离子改性吸附剂硫容上升。在模拟油中硫容从未改性的 13．4 mg／g提高到35．4 mg／g。通过热重分析发现，S—M键的形成是选择性吸附脱硫的关键。 关键词 竞争吸附 甲基叔丁基醚 二甲基二硫醚 ZSM一5 吸附脱硫 中图分类号：TE624．9 文献标志码：A DOI：10．3969／j．issn．1007—3426．2015．06．004 Study on selective adsorption desulfurization of MTBE Lu Yannan，Shi Li，Meng Xuan (Petroleum Processing Research Center，East China University of Science and Technology，Shanghai 200237，China) Abstract：The adsorption remova1 performance of DMDS from MTBE solution with various zeolites under the room conditions was studied．The results showed only ZSM一5 exhibited an exce11ent performance tO remove DMDS from MTBE selectively for the strong competitive adsorption of MTBE，and yet other zeolites showed totally futile．The shape～selectivity should be responsible for the selective adsorption of ZSM一5．Effect of modification by transition metals loaded on ZSM一5 was studied．Only the adsorbent with Ag loading showed a positively enhanced capacity of selective sulfur adsorption among all adsorbents studied．The sulfur capacity was increased from 13．4 mg／g to 35．4 mg／g adsorbent in the simulation MTBE solution after modification by Ag ．TGA～DSC analysis demonstrated the adsorption on the adsorbent occurred significantly via S—M bonds． Key words：competitive adsorption，MTBE，DMDS，ZSM一5，adsorption desulfurization 商品汽油中含有多种添加剂以提高其辛烷值，保