PRO／II软件研究碳酸二甲酯-甲醇体系和氨-甲醇体系的汽液平衡-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2014年第43卷第5期 PETR0CHEMICAL TECHN0LOGY ·523· 应用PRO／Ⅱ软件研究碳酸二甲酯一甲醇体系和 氨一甲醇体系的汽液平衡 刘 丹，韩 晖 (亚申科技研发中心(上海)有限公司，上海 201203) [摘要]采用化工流程模拟软件PRO／II对常压下碳酸二甲酯(DMC)一甲醇汽液平衡数据进行关联，考虑最低共沸点和甲醇沸 点间汽液平衡数据的权重关系，回归得到了NRTL模型的二元交互参数，模型的计算值与实验值吻合较好，甲醇气相组成的平 均相对偏差为0．13％，温度的平均相对偏差为0．04％。提出了氨一甲醇体系汽液平衡的研究在尿素醇解法制备DMC分离工艺中 的重要性，对文献报道的氨一甲醇汽液平衡数据进行关联，得到了Wilson模型的二元交互作用参数，所得参数可在较宽温度和 压力范围内使用。对碳酸二甲酯一甲醇体系、氨一甲醇体系所建立的模型可靠，可为工业生产提供理论指导。 [关键词]碳酸二甲酯；甲醇；氨；共沸物；汽液平衡；流程模拟；PRO／1I软件 [文章编号]1000—8144(2014)05—0523—07 [中图分类号]TQ 013．1 [文献标志码]A Study on Vapor·-Liquid Equilibrium of Dimethyl Carbonate--Methanol and Ammonia—Methanol Systems Using PRO／ⅡSoftware Liu Dan，Han Hui (Yashentech Corporation，Shanghai 201203，China) [Abstract]Reported vapor-liquid equilibrium data of dimethyl carbonate-methanol(DMC-MeOH) under normal pressure were correlated using the chemical process simulation software PRO／II． Based on the relationship between the lowest azeotropic point and boiling point of methanol， binary interaction parameters of the NRTL thermodynamic model were obtained by regression and the results were in agreement with experimental data．The correlated results showed that the average relative deviation of methanol vapor phase composition was 0．1 3％．and the average relative deviation of temperature was O．04％．The importance of the vapor-liquid equilibrium data of ammonia— methanol(NH3一MeOH)in the separation process of DMC synthesized by the urea alcoholysis was proposed．Reported vapor-liquid equilibrium data of NH3一MeOH system were correlated