分化试验课后习题谜底(国外英文资料).docVIP

分化实验课后习题答案(国外英文资料) Magnesium 2 trace magnesium 2 + of + - EDTA can be replaced by Ca2 +, and the stability of magnesium 2 + and chrome black T greater than that of Ca2 + and chrome black T, therefore, is ultimately magnesium 2 + and chrome black T color, the end of the becomes between magnesium 2 + and chrome black T discolored and more acute. Why should titration be done in a buffer solution? Answer: control PH, avoid the influence of other ions, the indicator color is also associated with PH. Water hardness measurement What kind of reference material is best used in this experiment to calibrate EDTA? Why? Answer: with calcium carbonate, the analysis of the water hardness refers to the amount of calcium and magnesium in water, the benchmark material consistent with the material being measured, the same analysis method, the analysis of the same element, so cause the least amount of error. 2. A: plus three acetic acid amine purpose is masking iron and aluminum, but need to join in acidic environment, if you join the buffer solution, the three acetic acid amine for masking effect, iron, aluminum ion will consume more EDTA, and makes the finish is not obvious. Determination of total iron content in iron ore 1, why is it that potassium chromate (k2cr2o7) can be used directly to make an accurate concentration solution? A: because the potassium bichromate is stable and the purity is high. It is a typical common reference material. Why do you want to add H3PO4 before titration? Why do you titrate immediately after joining H3PO4 Answer: can be generated in the process of complexometric titration titration before joining phosphoric acid ferric iron, making it the colorless phosphate complex, make the color of the titration end point without interference, at the same time reduce the ferric iron electric digits, that end in advance, not to make the finish more acute and sudden change. The time is long, and the masked iron ions are released, not ideal. When using SnCL2, why do