聚磷腈的研究及应用.pdfVIP

Vol.38 No.3 　　　　　 38 3 ·22 · NEW CH EM ICAL MATERIA LS 2010 3 续　通　毛庆辉　毛志平 (东华大学化学化工与生物工程学院, 上海201620) 　　聚磷腈系列的高分子材料 于其特殊的结构, 赋予了各种不同的性能, 因而具有在不同领域的应用潜在, 且 有些产品已开始使用,有些有待进一步探索。本文论述了聚磷腈材料科学的发展。主要包括聚磷腈材料的分子结构特 点,特殊性能, 应用领域等。聚磷腈可用于光学材料, 导电材料, 生物医药材料等方面。 　聚磷腈, 光学材料, 导电材料, 生物医药材料 Research and application of polyphosphazenes Xu Tong 　M ao Qinghui 　M ao Zhi ing (Chemistry and Chemical Engineering and Biological Engineering College of Donghua University, Shanghai 201620) Abstract 　For the s ecial structure of its trunk chain, oly hos hazenes can be given a great deal of character, so it can be used in a lot of areas.In addition, some of them have been used, and others still need being studied.The ex anding sco e of oly hos hazenes in materials science w as described in this artical.This ex ansion involved structure, characteris- tics and a lication that include hotorefractive materials, olymer electrolytes, biomedical materials and so on. Key words　oly hos hazene, hotorefractive material, olymer electrolyte, biomedical material 　　, 。 (LCST );(3), 20 60 , , , , , , 700 , , , 。 , ;(4), 。 , , 。 。 。 LCST, , 。, LCST [2] , , (1) : 。, Tlcst = a [ x logK+ (2 x )K] + b (1) 。, , Tlcst;a, b ;x