X射线荧光光谱法测定钛酸钡中主次元素含量_邱淼淼 - 副本.pdfVIP

40 1 Vol. 40 No. 1 2011 1 App lied Chem ical Industry Jan. 2011 X 1 1 1 1 1, 2 邱淼淼 , 吕述娇 , 郭丽, 周昳 , 商少明 ( 1. , 214122; 2. , 210094) : X BaTiO BaTi MgSi FeSr 3 , (\ 99. 99% ), , , , 6. 73% : X ; ; : TQ 649 : A : 1671- 3206( 2011) 01- 0170- 03 X-ray fluorescence spectrometry analysis for major and m inor components in barium titanate 1 1 1 1 1, 2 QI UM iao-m iao , L B S hu-j iao , G UO L i , ZH OU Yi , SHAN G S hao-m ing ( 1. School of Chem ical and M aterial Engineering, Jiangnan Un ivers ity, Wuxi 214122, Ch ina; 2. School of Chem ical Engineering, N anjing University of Science Technology, N anjing 210094, China) Abstract: A method for the determ ination of Ba, T ,iMg, S,i Fe, Sr in arium titanate by X-ray fluorescence spectrometry w as introduced. The sample pow derw as d irectly pressed into d iscs and used in the analysis. Based on the content range of major and m inor chem ical components in arium titanate, the calibration sample seriesw ere prepared by add ing a range of different volumes of standard solution of mi purity ele- ments to h igh purity arium titanate, wh ichw as a solution to the lack of standard samp les. M atrix effectw as corrected by emp irical coefficient method. The pressure of tablet mach ine and matrix effect w ere d is- cussed. The proposed method w as applied to determ ine the major