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4. (a) H3O++M-H+e M+H2O+H2 电化学脱附机理 Heyrovsky反应 (b) M-H + M-H 2M + H2 表面复合脱附机理 Tafel反应 3. H3O+ + M + e M-H + H2O 迟缓放电机理 Volmer反应 3, 4(a), 4(b) 皆可能为速度控制步骤 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 当4(b)为控制步骤 2H+ + 2e 2Had M-H + M-H 2M + H2 Had + Had H2 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. (忽略逆过程) Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 一些金属上氢阴极析出时塔菲尔公式中常数 a和b值(t=20±0.2°C, i = 1 Acm-2) Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 电流-超电势曲线 i i Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 液相中的三种传质过程 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 11-18 浓差极化 反应物质传输量 J = J扩 + J迁 + J流 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Ox + ze Red k1 k-1 Ox传输速率 r ? r迁 + r扩 (忽略对流) Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Fick第一定律 (稳态时) (D 为扩散系数) Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. P.415 还原过程的浓度及扩散层厚度 Evaluation only. Created with Aspose.Slides for .NET 3.5 Cl