第六讲 H离子浓度的计算3.pptVIP

* * * * * * * * * * * 强碱(NaOH) +弱碱(B-) 质子条件: [H+] + [HB] + cNaOH = [OH-] 忽略弱碱的离解: [OH-] ≈ c(NaOH) (最简式) Kw [OH-]= cHCl+ + Kbcb Kb+[OH-] [OH-] 两弱酸(HA+HB)溶液 质子条件: [H+] = [A-] + [B-] + [OH-] [HA]≈ cHA [HB]≈cHB 酸碱平衡关系 Kw KHA[HA] [H+]= + + KHB[HB] [H+] [H+] [H+] [H+]＝ KHAcHA [H+]＝ KHAcHA+KHBcHB KHAcHAKHBcHB 弱酸+弱碱(HA+B-)溶液 质子条件: [H+] + [HB] = [A-] + [OH-] [HA]≈ cHA [HB]≈cHB 酸碱平衡关系 Kw [H+][HB] [H+]+ = + KHA[HA] KHB [H+] [H+] [H+]＝ KHAKHBcHA/cB 综合考虑、分清主次、合理取舍、近似计算 酸碱溶液[H+]的计算总结 质子条件 物料平衡 电荷